11,14,35,38-Tetraoxaoctatetraconta-1,23,25,47-tetrayne, 13,36-bis[[(4-methoxyphenyl)methoxy]methyl]-, (13R,36S)-rel-

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Chemical Name:11,14,35,38-Tetraoxaoctatetraconta-1,23,25,47-tetrayne, 13,36-bis[[(4-methoxyphenyl)methoxy]methyl]-, (13R,36S)-rel-
CAS No.:486403-24-1
Molecular Formula:C62H94O8
Molecular Weight:967.424
Hs Code.:

Synonyms:

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Chemical Property of 11,14,35,38-Tetraoxaoctatetraconta-1,23,25,47-tetrayne, 13,36-bis[[(4-methoxyphenyl)methoxy]methyl]-, (13R,36S)-rel-

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Technology Process of 11,14,35,38-Tetraoxaoctatetraconta-1,23,25,47-tetrayne, 13,36-bis[[(4-methoxyphenyl)methoxy]methyl]-, (13R,36S)-rel-

There total 12 articles about 11,14,35,38-Tetraoxaoctatetraconta-1,23,25,47-tetrayne, 13,36-bis[[(4-methoxyphenyl)methoxy]methyl]-, (13R,36S)-rel- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 119227-71-3
9-decynyl mesylate

: 486403-21-8
(S)-2-{20-[(R)-1-Hydroxymethyl-2-(4-methoxy-benzyloxy)-ethoxy]-icosa-9,11-diynyloxy}-3-(4-methoxy-benzyloxy)-propan-1-ol

: 486403-24-1
C₆₂H₉₄O₈

Guidance literature:: With sodium hydride; In dimethyl sulfoxide; at 20 ℃; for 14h;
DOI:10.1055/s-2002-32987

Reference yield:

: 109786-76-7
(R)-4-(((4-methoxybenzyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolane

: 486403-24-1
C₆₂H₉₄O₈

Guidance literature:: Multi-step reaction with 7 steps

1: p-TsOH / methanol / 36 h / 20 °C

2: 89 percent / pyridine; DMAP / 13 h / 80 °C

3: 92 percent / NaH; TBAI / dimethylformamide / 19 h / 20 °C

4: 91 percent / I₂; morpholine / benzene / 11 h / 40 °C

5: 62 percent / CuI; pyrrolidine / -20 °C

6: p-TsOH / CH₂Cl₂; methanol / 19 h / 20 °C

7: 53 percent / NaH / dimethylsulfoxide / 14 h / 20 °C

With pyrrolidine; morpholine; pyridine; dmap; copper(l) iodide; iodine; tetra-(n-butyl)ammonium iodide; sodium hydride; toluene-4-sulfonic acid; In methanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; benzene;
DOI:10.1055/s-2002-32987

Reference yield:

: 109786-77-8
(S)-3-((4-methoxybenzyl)oxy)propane-1,2-diol

: 486403-24-1
C₆₂H₉₄O₈

Guidance literature:: Multi-step reaction with 6 steps

1: 89 percent / pyridine; DMAP / 13 h / 80 °C

2: 92 percent / NaH; TBAI / dimethylformamide / 19 h / 20 °C

3: 91 percent / I₂; morpholine / benzene / 11 h / 40 °C

4: 62 percent / CuI; pyrrolidine / -20 °C

5: p-TsOH / CH₂Cl₂; methanol / 19 h / 20 °C

6: 53 percent / NaH / dimethylsulfoxide / 14 h / 20 °C

With pyrrolidine; morpholine; pyridine; dmap; copper(l) iodide; iodine; tetra-(n-butyl)ammonium iodide; sodium hydride; toluene-4-sulfonic acid; In methanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; benzene;
DOI:10.1055/s-2002-32987