4-(CyclopropylideneMethyl)-N,N-diMethylaniline

Base Information

• Chemical Name: 4-(CyclopropylideneMethyl)-N,N-diMethylaniline
• CAS No.: 488800-44-8
• Molecular Formula: C12H15N
• Molecular Weight: 173.25400
• Hs Code.: 2921420090
• Mol file: 488800-44-8.mol

Synonyms:

Chemical Property of 4-(CyclopropylideneMethyl)-N,N-diMethylaniline

Chemical Property:

• PSA: 3.24000
• LogP: 2.92980

Purity/Quality:

98% ^*data from raw suppliers

4-(Cyclopropylidenemethyl)-N,N-dimethylaniline 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-(CyclopropylideneMethyl)-N,N-diMethylaniline

There total 1 articles about 4-(CyclopropylideneMethyl)-N,N-diMethylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-dimethylamino-benzaldehyde (100-10-7) + pentachlorophenyl cyclopropyl sulfone (688358-89-6) → 4-dimethylaminobenzylidenecyclopropane (488800-44-8)

Guidance literature:

With potassium tert-butylate; In N,N-dimethyl-formamide; at -35 - 60 ℃;

DOI:10.1055/s-2008-1042758;

Reference yield: 72.0%

4-dimethylaminobenzylidenecyclopropane (488800-44-8) → [4-(3-bromo-2-bromomethyl-propenyl)-phenyl]-dimethyl-amine + [4-((Z)-2,4-Dibromo-but-1-enyl)-phenyl]-dimethyl-amine

Guidance literature:

With copper(ll) bromide; In water; acetonitrile; at 85 ℃; for 14h;

DOI:10.1021/ol026911q

Reference yield: 43.0%

4-dimethylaminobenzylidenecyclopropane (488800-44-8) → 2-[(E)-2-(4-Dimethylamino-phenyl)-vinyl]-2-methoxy-3-[1-phenyl-meth-(E)-ylidene]-cyclopentanone

Guidance literature:

With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; In N,N-dimethyl-formamide; at 0 ℃; for 1.5h;

DOI:10.1021/ol061559s

upstream raw materials:

4-dimethylamino-benzaldehyde

pentachlorophenyl cyclopropyl sulfone

Refernces