2-Pentenoic acid, 5-(((dimethoxyphosphinyl)acetyl)oxy)-3-methyl-, (E)-

Base Information

Chemical Name:2-Pentenoic acid, 5-(((dimethoxyphosphinyl)acetyl)oxy)-3-methyl-, (E)-
CAS No.:88968-94-9
Molecular Formula:C₁₀H₁₇O₇P
Molecular Weight:280.215
Hs Code.:

Synonyms:2-Pentenoic acid, 5-(((dimethoxyphosphinyl)acetyl)oxy)-3-methyl-, (E)-;88968-94-9

Suppliers and Price of 2-Pentenoic acid, 5-(((dimethoxyphosphinyl)acetyl)oxy)-3-methyl-, (E)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 2-Pentenoic acid, 5-(((dimethoxyphosphinyl)acetyl)oxy)-3-methyl-, (E)-

Chemical Property:

Vapor Pressure:3.57E-09mmHg at 25°C
Boiling Point:445.3°Cat760mmHg
Flash Point:223.1°C
PSA：108.94000
Density:1.262g/cm³
LogP:1.43650
XLogP3:0.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:9
Exact Mass:280.07118987
Heavy Atom Count:18
Complexity:366

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=CC(=O)O)CCOC(=O)CP(=O)(OC)OC
Isomeric SMILES:C/C(=C\C(=O)O)/CCOC(=O)CP(=O)(OC)OC

Technology Process of 2-Pentenoic acid, 5-(((dimethoxyphosphinyl)acetyl)oxy)-3-methyl-, (E)-

There total 2 articles about 2-Pentenoic acid, 5-(((dimethoxyphosphinyl)acetyl)oxy)-3-methyl-, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 88969-03-3
(E)-5-[2-(Dimethoxy-phosphoryl)-acetoxy]-3-methyl-pent-2-enoic acid 2,2,2-trichloro-ethyl ester

: 88968-94-9
(E)-5-[2-(Dimethoxy-phosphoryl)-acetoxy]-3-methyl-pent-2-enoic acid

Guidance literature:: With potassium dihydrogenphosphate; zinc; In tetrahydrofuran;
DOI:10.1021/jo00153a035

Reference yield:

: 88968-95-0
2,2,2-Trichloroethyl 5-Hydroxy-3-methyl-2(E)-pentenoate

: 88968-94-9
(E)-5-[2-(Dimethoxy-phosphoryl)-acetoxy]-3-methyl-pent-2-enoic acid

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / Trifluoroacetic anhydride, Pyridine / CH₂Cl₂

2: 76 percent / Zn, KH₂PO₄ / tetrahydrofuran

With pyridine; potassium dihydrogenphosphate; trifluoroacetic anhydride; zinc; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00153a035

Reference yield: 19.0%

: 88968-94-9
(E)-5-[2-(Dimethoxy-phosphoryl)-acetoxy]-3-methyl-pent-2-enoic acid

: 2198-92-7
Verrucarol

: 84303-86-6,89015-96-3,89103-57-1
C₂₁H₂₈O₅

: 84303-87-7
C₁₉H₂₉O₈P

: 84303-84-4,84303-85-5
Trichothecene monoester

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; Title compound not separated from byproducts;
DOI:10.1021/jo00153a035