Phosphinous acid, diphenyl-, cyclopropylmethyl ester

Base Information

• Chemical Name: Phosphinous acid, diphenyl-, cyclopropylmethyl ester
• CAS No.: 494769-10-7
• Molecular Formula: C16H17OP
• Molecular Weight: 256.284
• Mol file: 494769-10-7.mol

Synonyms:

Chemical Property of Phosphinous acid, diphenyl-, cyclopropylmethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phosphinous acid, diphenyl-, cyclopropylmethyl ester

There total 1 articles about Phosphinous acid, diphenyl-, cyclopropylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

Cyclopropylmethanol (2516-33-8) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → C16H17OP (494769-10-7)

Guidance literature:

Cyclopropylmethanol; With n-butyllithium; In diethyl ether; hexane; at 0 ℃; for 1h;

chloro-diphenylphosphine; In diethyl ether; hexane; Further stages.;

DOI:10.1021/ja028912j

Reference yield:

C16H17OP (494769-10-7) → (3-butenyloxy)diphenylphosphane (126135-72-6)

Guidance literature:

Wilkinson's catalyst; at 130 ℃;

DOI:10.1021/ja028912j

Reference yield:

C16H17OP (494769-10-7) → C22H33OPSi

Guidance literature:

Multi-step reaction with 2 steps

1: (PPh₃)3RhCl / 130 °C

2: t-BuOOH / (PPh₃)3RhCl

With tert.-butylhydroperoxide; Wilkinson's catalyst;

DOI:10.1021/ja028912j

upstream raw materials:

Cyclopropylmethanol

chloro-diphenylphosphine

Downstream raw materials:

(3-butenyloxy)diphenylphosphane