(Z,Z)-Heptadeca-1,8,11-triene

Base Information

Chemical Name:(Z,Z)-Heptadeca-1,8,11-triene
CAS No.:56134-03-3
Molecular Formula:C17H30
Molecular Weight:234.425
Hs Code.:
European Community (EC) Number:260-005-0
DSSTox Substance ID:DTXSID101015918
Wikidata:Q67879839
Mol file:56134-03-3.mol

Synonyms:Dihydroaplotaxene;(Z,Z)-Heptadeca-1,8,11-triene;56134-03-3;1,8,11-Heptadecatriene, (Z,Z)-;(Z,Z)-1,8,11-Heptadecatriene;EINECS 260-005-0;Dihydro-aplotaxene;C17-H30;1E,8Z,11Z-heptadecatriene;XFZBIINLEPBMDY-NERFDCTISA-N;DTXSID101015918;Q67879839

Suppliers and Price of (Z,Z)-Heptadeca-1,8,11-triene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of (Z,Z)-Heptadeca-1,8,11-triene

Chemical Property:

Vapor Pressure:0.00107mmHg at 25°C
Boiling Point:310.9°Cat760mmHg
Flash Point:135.1°C
PSA：0.00000
Density:0.804g/cm³
LogP:6.20570
XLogP3:7.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:12
Exact Mass:234.234750957
Heavy Atom Count:17
Complexity:198

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCCC=CCC=CCCCCCC=C
Isomeric SMILES:CCCCC/C=C\C/C=C\CCCCCC=C

Technology Process of (Z,Z)-Heptadeca-1,8,11-triene

There total 7 articles about (Z,Z)-Heptadeca-1,8,11-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 60-33-3,116745-32-5,26085-09-6,64080-88-2,7049-66-3,949900-18-9,60476-23-5,6144-28-1,67922-65-0,89718-18-3
linoleic acid

: 56134-03-3
(Z,Z)-1,8,11-heptadecatriene

Guidance literature:: With dichloro(dimethylglyoxime)(dimethylglyoximato)cobalt(III); 9-mesitylacridine; In dichloromethane; acetonitrile; at 25 - 27 ℃; for 36h; Reagent/catalyst; Irradiation;
DOI:10.1021/acscatal.9b02951

Reference yield:

: 26001-58-1
(Z)-oct-2-en-1-ol

: 56134-03-3
(Z,Z)-1,8,11-heptadecatriene

Guidance literature:: Multi-step reaction with 6 steps

1: PBr₃, pyridine / diethyl ether

2: 1a.) ethylmagnesium bromide, 1b.) cuprous chloride / 1a.) THF, reflux, 6 h, 1b.) 0 deg C, 15 min, 3.) reflux, 9 h

3: 66 percent / p-TsOH / methanol / 4 h / Heating

4: 92 percent / H₂, quinoline / Lindlar's catalyst / hexane / Ambient temperature

5: 81 percent / triethylamine / CH₂Cl₂ / 0.5 h / -5 °C

6: 1.) Mg, iodine, 2.) HMPA / 1.) THF, 40-50 deg C, 1.5 h, 2.) 0-10 deg C, 30 min, 3.) RT, overnight

With pyridine; quinoline; N,N,N,N,N,N-hexamethylphosphoric triamide; ethylmagnesium bromide; hydrogen; iodine; phosphorus tribromide; toluene-4-sulfonic acid; magnesium; triethylamine; copper(l) chloride; Lindlar's catalyst; In methanol; diethyl ether; hexane; dichloromethane;

Reference yield:

: 25466-54-0,53645-21-9,56318-83-3
(Z)-1-bromo-2-octene

: 56134-03-3
(Z,Z)-1,8,11-heptadecatriene

Guidance literature:: Multi-step reaction with 5 steps

1: 1a.) ethylmagnesium bromide, 1b.) cuprous chloride / 1a.) THF, reflux, 6 h, 1b.) 0 deg C, 15 min, 3.) reflux, 9 h

2: 66 percent / p-TsOH / methanol / 4 h / Heating

3: 92 percent / H₂, quinoline / Lindlar's catalyst / hexane / Ambient temperature

4: 81 percent / triethylamine / CH₂Cl₂ / 0.5 h / -5 °C

5: 1.) Mg, iodine, 2.) HMPA / 1.) THF, 40-50 deg C, 1.5 h, 2.) 0-10 deg C, 30 min, 3.) RT, overnight

With quinoline; N,N,N,N,N,N-hexamethylphosphoric triamide; ethylmagnesium bromide; hydrogen; iodine; toluene-4-sulfonic acid; magnesium; triethylamine; copper(l) chloride; Lindlar's catalyst; In methanol; hexane; dichloromethane;