Iron,tetracarbonyl(triphenylarsine)-

Base Information

Chemical Name:Iron,tetracarbonyl(triphenylarsine)-
CAS No.:14375-84-9
Molecular Formula:C₂₂H₁₅AsFeO₄
Molecular Weight:474.127
Hs Code.:
DSSTox Substance ID:DTXSID401296404

Synonyms:Iron,tetracarbonyl(triphenylarsine)-;Tetracarbonyl(triphenylarsine)iron;DTXSID401296404;14375-84-9

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Chemical Property of Iron,tetracarbonyl(triphenylarsine)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:473.953564
Heavy Atom Count:28
Complexity:370

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)[As](C2=CC=CC=C2)C3=CC=CC=C3.[Fe]

Technology Process of Iron,tetracarbonyl(triphenylarsine)-

There total 8 articles about Iron,tetracarbonyl(triphenylarsine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 603-32-7
triphenyl-arsane

: 14375-84-9,35644-25-8
Fe(CO)4(As(C₆H₅)3)

Guidance literature:: cobalt(II)-iodide * 4 H₂O; In toluene; ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 0.5 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;
DOI:10.1016/S0022-328X(00)93454-5

Reference yield: 15.0%

: 20516-72-7,14375-85-0
(As(C₆H₅)3)2Fe(CO)3

: 14375-84-9,35644-25-8
Fe(CO)4(As(C₆H₅)3)

Guidance literature:: With Ag[PF₆]; In dichloromethane; filtered, evapd., recrystd. from hexane;
DOI:10.1039/DT9800000579

Reference yield:

: 13463-40-6,71564-23-3,37220-42-1
iron pentacarbonyl

: 603-32-7
triphenyl-arsane

: 14375-84-9,35644-25-8
Fe(CO)4(As(C₆H₅)3)

Guidance literature:: With sodium tetrahydroborate; In tetrahydrofuran; NaBH4 and AsPh3 were added to Fe(CO)5 (molar ratio 0.45:1:1.5) in THF, stirred under Ar at room temp. for 1 h, heated at 75°C for 48 h; cooled to room temp., filtered through alumina column, washed with CH2Cl2, eluant concd. in vac., dissolved in CH2Cl2, chromd. over neutral alumina, eluted with hexane and hexane-benzene, concd. in vac., recrystd. from boiling heptane; elem. anal.;