Stannane, trimethyl[1-methylene-2-(phenylethynyl)hexyl]-

Base Information

Chemical Name:Stannane, trimethyl[1-methylene-2-(phenylethynyl)hexyl]-
CAS No.:498547-51-6
Molecular Formula:C18H26Sn
Molecular Weight:361.114
Hs Code.:

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Chemical Property of Stannane, trimethyl[1-methylene-2-(phenylethynyl)hexyl]-

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Technology Process of Stannane, trimethyl[1-methylene-2-(phenylethynyl)hexyl]-

There total 2 articles about Stannane, trimethyl[1-methylene-2-(phenylethynyl)hexyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 2384-90-9
1,2-Heptadiene

: 1199-95-7
1-(trimethylstannyl)-2-phenylethyne

: 869334-42-9,498547-52-7
(C₄H₉)CHC(Sn(CH₃)3)CH₂C₂(C₆H₅)

: 498547-51-6
3-butyl-5-phenyl-2-trimethylstannyl-1-penten-4-yne

Guidance literature:: With Ni(C₈H₁₂)2/CH₂(CH₂P(C₆H₅)2)2; In toluene; treatment of (C6H5)C2Sn(CH3)3 with 5 mol% of Ni(C8H12)2 - C3H6(P(C6H5)2)2 under atmosphere of (C4H9)CHCCH2 in toluene at 30 °C for 10 h;
DOI:10.1039/b206240b

Reference yield:

: 2384-90-9
1,2-Heptadiene

: 1199-95-7
1-(trimethylstannyl)-2-phenylethyne

: 498547-52-7,869334-42-9
(Z)-1-phenyl-4-trimethylstannyl-4-nonen-1-yne

: 498547-51-6
3-butyl-5-phenyl-2-trimethylstannyl-1-penten-4-yne

Guidance literature:: With catalyst: Ni(COD)2-Me₂P(CH₂)3PMe₂; In toluene; alkynylstannane and 1,2-diene (molar ratio 1:1.5) reacted in toluene in presence of Ni complex (0.05 equiv.) and phosphine (0.05 equiv.) at 30°C for 10 h; detd. by (119)Sn NMR spectra; PhC2CH(Bu)C(CH2)SnMe3 and PhC2CH2C(SnMe3)CHBu (32:68) obtained, total yield 82%;
DOI:10.1246/bcsj.75.1435

Reference yield: 82.0%

: 498547-51-6
3-butyl-5-phenyl-2-trimethylstannyl-1-penten-4-yne

: 498547-55-0
4,7-dibutyl-4,5-dimethylene-1,8-diphenyl-1,7-octadiyne

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(l) chloride; copper dichloride; In dimethyl sulfoxide; at 50 ℃; for 3h;
DOI:10.1016/j.jorganchem.2004.07.037