D-Ribofuranoside, methyl 2,3-O-(1-methylethylidene)-,4-methylbenzenesulfonate

Base Information

Chemical Name:D-Ribofuranoside, methyl 2,3-O-(1-methylethylidene)-,4-methylbenzenesulfonate
CAS No.:6953-71-5
Molecular Formula:C₁₆H₂₂O₇S
Molecular Weight:358.412
Hs Code.:
European Community (EC) Number:603-383-8
NSC Number:85192,39263
DSSTox Substance ID:DTXSID60989504

Synonyms:6953-71-5;D-Ribofuranoside, methyl 2,3-O-(1-methylethylidene)-,4-methylbenzenesulfonate;13007-50-6;NSC-85192;NSC39263;NCIOpen2_009322;SCHEMBL13290042;DTXSID60989504;NSC85192;NSC-39263;Methyl 5-O-(4-methylbenzene-1-sulfonyl)-2,3-O-(1-methylethylidene)pentofuranoside;FT-0671876

Suppliers and Price of D-Ribofuranoside, methyl 2,3-O-(1-methylethylidene)-,4-methylbenzenesulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of D-Ribofuranoside, methyl 2,3-O-(1-methylethylidene)-,4-methylbenzenesulfonate

Chemical Property:

XLogP3:1.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:5
Exact Mass:358.10862421
Heavy Atom Count:24
Complexity:533

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)(=O)OCC2C3C(C(O2)OC)OC(O3)(C)C

Technology Process of D-Ribofuranoside, methyl 2,3-O-(1-methylethylidene)-,4-methylbenzenesulfonate

There total 5 articles about D-Ribofuranoside, methyl 2,3-O-(1-methylethylidene)-,4-methylbenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 4099-85-8,5531-21-5,20672-63-3,20672-65-5,58763-00-1,63029-07-2,72402-14-3,84894-45-1,129263-68-9,828937-29-7
methyl 2,3-O-isopropylidene-D-ribofuranoside

: 98-59-9
p-toluenesulfonyl chloride

: 4137-56-8,5531-22-6,6953-71-5,52631-00-2,63087-95-6,84894-43-9,13007-50-6
((3aR,4R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methyl 4-methylbenzenesulfonate

Guidance literature:: With pyridine; at -10 - -5 ℃; for 4h; Concentration; Time; Temperature;

Reference yield:

: 532-20-7,613-83-2,7261-25-8,7687-39-0,13221-22-2,14795-83-6,15761-67-8,20074-49-1,25545-03-3,25545-04-4,32445-75-3,34436-17-4,36441-93-7,36468-53-8,37110-85-3,37388-49-1,38029-69-5,40461-77-6,40461-89-0,41546-19-4,41546-20-7,41546-21-8,41546-26-3,41546-29-6,41546-30-9,41546-31-0,126872-16-0,131064-98-7
D-Ribose

: 4137-56-8,5531-22-6,6953-71-5,52631-00-2,63087-95-6,84894-43-9,13007-50-6
((3aR,4R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methyl 4-methylbenzenesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1: perchloric acid / acetone / 24 h / Molecular sieve

2: pyridine / 24 h / 20 °C

With pyridine; perchloric acid; In acetone;
DOI:10.1016/j.bmcl.2012.04.050

Reference yield:

: 10257-32-6
D-ribose

: 4137-56-8,5531-22-6,6953-71-5,52631-00-2,63087-95-6,84894-43-9,13007-50-6
((3aR,4R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methyl 4-methylbenzenesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1: hydrogenchloride / 22 h / 25 °C

2: pyridine / 4 h / -10 - -5 °C

With pyridine; hydrogenchloride;