Technology Process of Stannane,
tributyl[(1E)-4-[(4-methoxyphenyl)methoxy]-1-methyl-1-butenyl]-
There total 1 articles about Stannane,
tributyl[(1E)-4-[(4-methoxyphenyl)methoxy]-1-methyl-1-butenyl]- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
E-5-hydroxy-2-tri-n-butylstannyl-2-pentene;
With
sodium hydride;
In
dimethyl sulfoxide;
at 0 - 20 ℃;
for 2h;
p-methoxybenzyl chloride;
With
tetra-(n-butyl)ammonium iodide;
at 20 ℃;
for 5h;
DOI:10.1002/ejoc.201402234
- Guidance literature:
-
With
tetrakis(triphenylphosphine) palladium(0); copper(I) thiophene-2-carboxylate; cesium fluoride;
In
N,N-dimethyl-formamide;
at 20 ℃;
for 1.5h;
Reagent/catalyst;
diastereoselective reaction;
DOI:10.1002/ejoc.201402234
- Guidance literature:
-
Multi-step reaction with 5 steps
1: tetrakis(triphenylphosphine) palladium(0); copper(I) thiophene-2-carboxylate; cesium fluoride / N,N-dimethyl-formamide / 1.5 h / 20 °C
2: lithium aluminium tetrahydride / tetrahydrofuran / 20 - 80 °C
3: pyridine-SO3 complex; pyridine; triethylamine / dichloromethane; dimethyl sulfoxide / 0.5 h / 0 - 20 °C
4: tetrahydrofuran; diethyl ether / 1 h / -30 °C
5: pyridine-SO3 complex; pyridine; triethylamine / dichloromethane; dimethyl sulfoxide / 1 h / 0 - 20 °C
With
pyridine; lithium aluminium tetrahydride; tetrakis(triphenylphosphine) palladium(0); copper(I) thiophene-2-carboxylate; pyridine-SO3 complex; triethylamine; cesium fluoride;
In
tetrahydrofuran; diethyl ether; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide;
1: |Stille Cross Coupling / 3: |Parikh-Doering Oxidation / 5: |Parikh-Doering Oxidation;
DOI:10.1002/ejoc.201402234
