5,10-Methanobenzocyclooctene, 5,10-dihydro-

Base Information

Chemical Name:5,10-Methanobenzocyclooctene, 5,10-dihydro-
CAS No.:33627-04-2
Molecular Formula:C₁₃H₁₂
Molecular Weight:168.238
Hs Code.:
DSSTox Substance ID:DTXSID80955261

Synonyms:33627-04-2;5,10-Methanobenzocyclooctene,5,10-dihydro-;5,10-Methanobenzocyclooctene, 5,10-dihydro-;DTXSID80955261;5,10-Dihydro-5,10-methanobenzo[8]annulene

Suppliers and Price of 5,10-Methanobenzocyclooctene, 5,10-dihydro-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 5,10-Methanobenzocyclooctene, 5,10-dihydro-

Chemical Property:

Vapor Pressure:0.00896mmHg at 25°C
Boiling Point:274.6°Cat760mmHg
Flash Point:116.1°C
Density:1.07g/cm³
XLogP3:3.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:168.093900383
Heavy Atom Count:13
Complexity:223

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C2C=CC=CC1C3=CC=CC=C23

Technology Process of 5,10-Methanobenzocyclooctene, 5,10-dihydro-

There total 4 articles about 5,10-Methanobenzocyclooctene, 5,10-dihydro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 105176-18-9
4b,9a-dihydro-5H-benzo<3,4>cyclobuta<1,2>cyclohepten

: 33627-04-2
benzo(7,8)bicyclo(4.2.1)nona-2,4,7-triene

Guidance literature:: With molybdenum hexacarbonyl; In tetrahydrofuran; for 0.666667h; Heating; var.: solvent, temperature, time, reagent;
DOI:10.1016/0022-328X(86)80007-9

Reference yield: 52.0%

: 41371-94-2,14974-11-9,96647-88-0
tris(ammonia)chromium tricarbonyl

: 105176-18-9
4b,9a-dihydro-5H-benzo<3,4>cyclobuta<1,2>cyclohepten

: tricarbonylchromium(benzo[7,8]bicyclo[4.2.1]nona-2,4,7-triene)

: 33627-04-2
benzo(7,8)bicyclo(4.2.1)nona-2,4,7-triene

Guidance literature:: In 1,4-dioxane; under Ar; mixt. of Cr-complex and triene in dioxane refluxed (6 h); filtration (SiO2), evapn., column chromy. (degassed silica, petrol ether/diethyl ether), crystn. (diethyl ether/petrol ether); elem. anal.;
DOI:10.1016/0022-328X(86)80007-9

Reference yield: 15.0%

: 16800-46-7,22736-49-8
trisacetonitrile(tricarbonyl)chromium⁽⁰⁾

: 105176-18-9
4b,9a-dihydro-5H-benzo<3,4>cyclobuta<1,2>cyclohepten

: tricarbonylchromium(benzo[7,8]bicyclo[4.2.1]nona-2,4,7-triene)

: 33627-04-2
benzo(7,8)bicyclo(4.2.1)nona-2,4,7-triene

Guidance literature:: In tetrahydrofuran; under Ar; addn. of triene in THF to Cr-complex, kept (40°C, 18 h); filtration (SiO2), evapn., column chromy. (degassed silica, petroleum ether/diethyl ether);
DOI:10.1016/0022-328X(86)80007-9