Tricyclo(8.2.2.24,7)hexadeca-6,10,12,13,15-hexaene, 5,6,11,12,13,15-hexamethyl-

Base Information

Chemical Name:Tricyclo(8.2.2.24,7)hexadeca-6,10,12,13,15-hexaene, 5,6,11,12,13,15-hexamethyl-
CAS No.:77897-17-7
Molecular Formula:C₂₂H₂₈
Molecular Weight:292.464
Hs Code.:
DSSTox Substance ID:DTXSID80228523
Wikidata:Q83108515

Synonyms:Tricyclo(8.2.2.24,7)hexadeca-6,10,12,13,15-hexaene, 5,6,11,12,13,15-hexamethyl-;77897-17-7;Tricyclo[8.2.2.24,7]hexadeca-6,10,12,13,15-hexaene, 5,6,11,12,13,15-hexamethyl-;DTXSID80228523;2,3,5,2',5',6'-Hexamethyl-[2.2]paracyclophane

Suppliers and Price of Tricyclo(8.2.2.24,7)hexadeca-6,10,12,13,15-hexaene, 5,6,11,12,13,15-hexamethyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Tricyclo(8.2.2.24,7)hexadeca-6,10,12,13,15-hexaene, 5,6,11,12,13,15-hexamethyl-

Chemical Property:

Vapor Pressure:4.86E-07mmHg at 25°C
Boiling Point:425.1°Cat760mmHg
Flash Point:234.9°C
Density:0.977g/cm³
XLogP3:6.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:292.219100893
Heavy Atom Count:22
Complexity:320

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=C(C2=C(C(=C1CCC3=C(C(=C(CC2)C=C3)C)C)C)C)C

Technology Process of Tricyclo(8.2.2.24,7)hexadeca-6,10,12,13,15-hexaene, 5,6,11,12,13,15-hexamethyl-

There total 12 articles about Tricyclo(8.2.2.24,7)hexadeca-6,10,12,13,15-hexaene, 5,6,11,12,13,15-hexamethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 102419-27-2,69684-86-2,37437-92-6
4,5,12,13-tetrakis(hydroxymethyl)<2.2>paracyclophane

: 77897-17-7,83602-33-9
5,6,11,13,14,16-Hexamethyl-tricyclo[8.2.2.2^4,7]hexadeca-1⁽¹³⁾,4⁽¹⁶⁾,5,7⁽¹⁵⁾,10⁽¹⁴⁾,11-hexaene

Guidance literature:: Multi-step reaction with 10 steps

1: 90 percent / PBr₃

2: 89 percent / LAH / tetrahydrofuran

3: 92 percent / TiCl₄ / 0 °C

4: 93 percent / LAH / tetrahydrofuran

5: 92 percent / PBr₃ / CH₂Cl₂

6: 88 percent / LAH / tetrahydrofuran

7: TiCl₄ / 0 °C

8: LAH / tetrahydrofuran

9: PBr₃ / CH₂Cl₂

10: LAH / tetrahydrofuran

With lithium aluminium tetrahydride; phosphorus tribromide; titanium tetrachloride; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(00)71150-6

Reference yield:

: 102419-26-1,69684-87-3,67903-66-6
4,5,12,13-tetrakis(bromomethyl)<2.2>paracyclophane

: 77897-17-7,83602-33-9
5,6,11,13,14,16-Hexamethyl-tricyclo[8.2.2.2^4,7]hexadeca-1⁽¹³⁾,4⁽¹⁶⁾,5,7⁽¹⁵⁾,10⁽¹⁴⁾,11-hexaene

Guidance literature:: Multi-step reaction with 9 steps

1: 89 percent / LAH / tetrahydrofuran

2: 92 percent / TiCl₄ / 0 °C

3: 93 percent / LAH / tetrahydrofuran

4: 92 percent / PBr₃ / CH₂Cl₂

5: 88 percent / LAH / tetrahydrofuran

6: TiCl₄ / 0 °C

7: LAH / tetrahydrofuran

8: PBr₃ / CH₂Cl₂

9: LAH / tetrahydrofuran

With lithium aluminium tetrahydride; phosphorus tribromide; titanium tetrachloride; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(00)71150-6

Reference yield:

: 71779-89-0,87554-56-1
4,5,15,16-tetramethyl<2.2>paracyclophane

: 77897-17-7,83602-33-9
5,6,11,13,14,16-Hexamethyl-tricyclo[8.2.2.2^4,7]hexadeca-1⁽¹³⁾,4⁽¹⁶⁾,5,7⁽¹⁵⁾,10⁽¹⁴⁾,11-hexaene

Guidance literature:: Multi-step reaction with 8 steps

1: 92 percent / TiCl₄ / 0 °C

2: 93 percent / LAH / tetrahydrofuran

3: 92 percent / PBr₃ / CH₂Cl₂

4: 88 percent / LAH / tetrahydrofuran

5: TiCl₄ / 0 °C

6: LAH / tetrahydrofuran

7: PBr₃ / CH₂Cl₂

8: LAH / tetrahydrofuran

With lithium aluminium tetrahydride; phosphorus tribromide; titanium tetrachloride; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(00)71150-6