Silane, [6-[4-(1,1-dimethylethyl)phenyl]-1,3,5-hexatriynyl]trimethyl-

Base Information

Chemical Name:Silane, [6-[4-(1,1-dimethylethyl)phenyl]-1,3,5-hexatriynyl]trimethyl-
CAS No.:501072-60-2
Molecular Formula:C19H22Si
Molecular Weight:278.469
Hs Code.:
DSSTox Substance ID:DTXSID00452282
Nikkaji Number:J1.880.317H
Wikidata:Q82272807

Synonyms:501072-60-2;Silane, [6-[4-(1,1-dimethylethyl)phenyl]-1,3,5-hexatriynyl]trimethyl-;DTXSID00452282;[6-(4-tert-Butylphenyl)-1,3,5-hexatriynyl]trimethylsilane

Suppliers and Price of Silane, [6-[4-(1,1-dimethylethyl)phenyl]-1,3,5-hexatriynyl]trimethyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silane, [6-[4-(1,1-dimethylethyl)phenyl]-1,3,5-hexatriynyl]trimethyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:5
Exact Mass:278.149077236
Heavy Atom Count:20
Complexity:519

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)C1=CC=C(C=C1)C#CC#CC#C[Si](C)(C)C

Technology Process of Silane, [6-[4-(1,1-dimethylethyl)phenyl]-1,3,5-hexatriynyl]trimethyl-

There total 4 articles about Silane, [6-[4-(1,1-dimethylethyl)phenyl]-1,3,5-hexatriynyl]trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 501072-54-4
[6,6-dibromo-5-(4-tert-butylphenyl)hex-5-ene-1,3-diynyl]trimethylsilane

: 501072-60-2
[6-(4-t-butylphenyl)-1,3,5-hexatriynyl]trimethylsilane

Guidance literature:: With n-butyllithium; In hexane; at -78 - -40 ℃;
DOI:10.1021/jo026481h

Reference yield:

: 1-(4-tert-butyl-phenyl)-5-trimethylsilanyl-penta-2,4-diyn-1-one

: 501072-60-2
[6-(4-t-butylphenyl)-1,3,5-hexatriynyl]trimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: PPh₃ / CH₂Cl₂ / Heating

2: 98 percent / n-BuLi / hexane / -78 - -40 °C

With n-butyllithium; triphenylphosphine; In hexane; dichloromethane; 2: Fritsch-Buttenberg-Wiechell rearrangement;
DOI:10.1021/jo026481h

Reference yield:

: 4526-07-2
1,4-bis(trimethylsilyl)-1,3-butadiyne

: 501072-60-2
[6-(4-t-butylphenyl)-1,3,5-hexatriynyl]trimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: AlCl₃ / CH₂Cl₂ / 3 h / 0 °C

2: PPh₃ / CH₂Cl₂ / Heating

3: 98 percent / n-BuLi / hexane / -78 - -40 °C

With n-butyllithium; aluminium trichloride; triphenylphosphine; In hexane; dichloromethane; 1: Friedel-Crafts acylation / 3: Fritsch-Buttenberg-Wiechell rearrangement;
DOI:10.1021/jo026481h