difluoroplatinum

Base Information

• Chemical Name: difluoroplatinum
• CAS No.: 18820-56-9
• Molecular Formula: F2Pt
• Molecular Weight: 0
• Mol file: 18820-56-9.mol

Synonyms:Platinumdifluoride

Chemical Property of difluoroplatinum

Chemical Property:

• PSA: 0.00000
• LogP: 0.83790

Purity/Quality:

99% ^*data from raw suppliers

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Refernces

Solution decomposition of platinum(II) fluoride cations; single-crystal structure of [Pt(PPh₃)₂(C₆H₄PPh ₂)][SbF₆]·CD₂Cl₂

10.1039/a709075g

The research investigates the solution decomposition of platinum(II) fluoride cations, specifically focusing on the complexes [PtF(PPh3)3][X] (where X = HF2, BF4, or SbF6). The study aims to evaluate the stability and reactivity of metal-fluoride bonds in these complexes, an area that has been relatively neglected compared to other halide ligands. The researchers used a combination of techniques, including mass spectrometry, multinuclear NMR spectroscopy, and single-crystal X-ray crystallography, to characterize the decomposition products. They found that the presence of water in solvents triggers the decomposition, initially forming [Pt(OH)(PPh3)3]X and subsequently leading to ortho-metallated products [Pt(PPh3)3(C6H4PPh2)][X].

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