2H-Pyran-3(6H)-one, 2-methyl-6-(phenylmethoxy)-, (2S,6R)-

Base Information

Chemical Name:2H-Pyran-3(6H)-one, 2-methyl-6-(phenylmethoxy)-, (2S,6R)-
CAS No.:512809-21-1
Molecular Formula:C13H14O3
Molecular Weight:218.252
Hs Code.:
DSSTox Substance ID:DTXSID50473149
Nikkaji Number:J1.887.436I
Wikidata:Q82302337
Mol file:512809-21-1.mol

Synonyms:2H-Pyran-3(6H)-one, 2-methyl-6-(phenylmethoxy)-, (2S,6R)-;512809-21-1;DTXSID50473149

Suppliers and Price of 2H-Pyran-3(6H)-one, 2-methyl-6-(phenylmethoxy)-, (2S,6R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 2H-Pyran-3(6H)-one, 2-methyl-6-(phenylmethoxy)-, (2S,6R)-

Chemical Property:

XLogP3:1.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:218.094294304
Heavy Atom Count:16
Complexity:266

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1C(=O)C=CC(O1)OCC2=CC=CC=C2
Isomeric SMILES:C[C@H]1C(=O)C=C[C@@H](O1)OCC2=CC=CC=C2

Technology Process of 2H-Pyran-3(6H)-one, 2-methyl-6-(phenylmethoxy)-, (2S,6R)-

There total 13 articles about 2H-Pyran-3(6H)-one, 2-methyl-6-(phenylmethoxy)-, (2S,6R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 865484-73-7
tert-butyl ((2S,6S)-6-methyl-5-oxo-5,6-dihydro-2H-pyran-2-yl) carbonate

: 100-51-6,185532-71-2
benzyl alcohol

: 512809-21-1
benzyl 2,3,6-trideoxy-α-L-hex-2-enopyranosid-4-ulose

Guidance literature:: With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; triphenylphosphine; In dichloromethane; at 0 ℃; for 8h;
DOI:10.1039/c1cc13837e

Reference yield: 92.0%

: (2S,6S)-6-methyl-5-oxo-5,6-dihydro-2H-pyran-2-yl isobutyrate

: 100-51-6,185532-71-2
benzyl alcohol

: 512809-21-1
benzyl 2,3,6-trideoxy-α-L-hex-2-enopyranosid-4-ulose

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenylphosphine; In dichloromethane; at 0 ℃; for 1h; stereospecific reaction; Inert atmosphere;
DOI:10.1021/acs.orglett.5b02641

Reference yield: 90.0%

: tert-butyl (6R)-5,6-dihydro-6-methyl-5-oxo-2H-pyran-2-yl carbonate

: 100-51-6,185532-71-2
benzyl alcohol

: 512809-21-1
benzyl 2,3,6-trideoxy-α-L-hex-2-enopyranosid-4-ulose

Guidance literature:: With triphenylphosphine; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In dichloromethane; at 0 - 20 ℃; for 2h;
DOI:10.1021/jo800691v