(1R-(1alpha,2alpha,5alpha))-6,6-Dimethylspiro(bicyclo(3.1.1)heptane-2,2'-oxirane)

Base Information

Chemical Name:(1R-(1alpha,2alpha,5alpha))-6,6-Dimethylspiro(bicyclo(3.1.1)heptane-2,2'-oxirane)
CAS No.:56246-58-3
Molecular Formula:C10H16 O
Molecular Weight:152.236
Hs Code.:
European Community (EC) Number:260-076-8
UNII:F85V8QAQ7S
DSSTox Substance ID:DTXSID901172401
Nikkaji Number:J269.366F

Synonyms:56246-58-3;F85V8QAQ7S;(1r,2s,5s)-6,6-dimethylspiro[bicyclo[3.1.1]heptane-2,2'-oxirane];EINECS 260-076-8;(1R-(1alpha,2alpha,5alpha))-6,6-Dimethylspiro(bicyclo(3.1.1)heptane-2,2'-oxirane);(1R,2S,5S)-7,7-Dimethylspiro(bicyclo(3.1.1)heptane-2,2'-oxirane);2,10 - epoxypinane;(1R,2S,5S)-6,6-DIMETHYLSPIRO(BICYCLO(3.1.1)HEPTANE-2,2'-OXIRANE);[1R-(1alpha,2alpha,5alpha)]-6,6-dimethylspiro[bicyclo[3.1.1]heptane-2,2'-oxirane];UNII-F85V8QAQ7S;DTXSID901172401;(+)-2(10)-PINENE OXIDE;(+)-2.ALPHA.,10-EPOXYPINANE;(1beta,5beta)-2beta,2-(Oxymethylene)-6,6-dimethylbicyclo[3.1.1]heptane;SPIRO(BICYCLO(3.1.1)HEPTANE-2,2'-OXIRANE), 6,6-DIMETHYL-, (1R,2S,5S)-

Suppliers and Price of (1R-(1alpha,2alpha,5alpha))-6,6-Dimethylspiro(bicyclo(3.1.1)heptane-2,2'-oxirane)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(+)-2α,10-Epoxypinane
5mg
$ 375.00

Total 4 raw suppliers

Chemical Property of (1R-(1alpha,2alpha,5alpha))-6,6-Dimethylspiro(bicyclo(3.1.1)heptane-2,2'-oxirane)

Chemical Property:

Boiling Point:202.1°Cat760mmHg
Flash Point:54.4°C
PSA：12.53000
Density:1.04g/cm³
LogP:2.21150
XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:152.120115130
Heavy Atom Count:11
Complexity:209

Purity/Quality:

99% ^*data from raw suppliers

(+)-2α,10-Epoxypinane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C2CCC3(C1C2)CO3)C
Isomeric SMILES:CC1([C@H]2CC[C@]3([C@@H]1C2)CO3)C
Uses (+)-2α,10-Epoxypinane is an intermediate in the synthesis of (2S)-(-)-cis-2-Pinanol (P458625), which is a monoterpene and a component of several plant essential oils.

Technology Process of (1R-(1alpha,2alpha,5alpha))-6,6-Dimethylspiro(bicyclo(3.1.1)heptane-2,2'-oxirane)

There total 5 articles about (1R-(1alpha,2alpha,5alpha))-6,6-Dimethylspiro(bicyclo(3.1.1)heptane-2,2'-oxirane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 18172-67-3,19902-08-0,25719-60-2
beta-pinene

: 56246-58-3
β-pinene oxide

Guidance literature:: With peracetic acid; sodium carbonate; In dichloromethane; at 0 - 5 ℃; for 2h;

Reference yield: 82.0%

: 18172-67-3,19902-08-0,25719-60-2
beta-pinene

: 56246-58-3
β-pinene oxide

: 4501-58-0,23727-15-3,91200-86-1,91819-58-8
campholenyc aldehyde

Guidance literature:: With pyridine; dihydrogen peroxide; methyltrioxorhenium(VII); In dichloromethane; water; at -0.15 ℃; for 1.2h; Yields of byproduct given;
DOI:10.1016/S0040-4039(98)01853-X