Methyl 2-(bromomethyl)-6,6-dimethyl-3-oxo-1-cyclohexene-1-carboxylate

Base Information

Chemical Name:Methyl 2-(bromomethyl)-6,6-dimethyl-3-oxo-1-cyclohexene-1-carboxylate
CAS No.:51799-97-4
Molecular Formula:C11H15BrO3
Molecular Weight:275.142
Hs Code.:
DSSTox Substance ID:DTXSID401157935

Synonyms:DTXSID401157935;Methyl 2-(bromomethyl)-6,6-dimethyl-3-oxo-1-cyclohexene-1-carboxylate;51799-97-4

Suppliers and Price of Methyl 2-(bromomethyl)-6,6-dimethyl-3-oxo-1-cyclohexene-1-carboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methyl 2-(bromomethyl)-6,6-dimethyl-3-oxo-1-cyclohexene-1-carboxylate

Chemical Property:

XLogP3:1.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:274.02046
Heavy Atom Count:15
Complexity:329

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1(CCC(=O)C(=C1C(=O)OC)CBr)C

Technology Process of Methyl 2-(bromomethyl)-6,6-dimethyl-3-oxo-1-cyclohexene-1-carboxylate

There total 10 articles about Methyl 2-(bromomethyl)-6,6-dimethyl-3-oxo-1-cyclohexene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 28120-76-5
methyl 2,6,6-trimethyl-3-oxocyclohex-1-ene-1-carboxylate

: 51799-97-4
Methyl-2-bromaethyl-6,6-dimethyl-3-oxocyclohex-1-en-1-carboxylat

Guidance literature:: With N-Bromosuccinimide; In tetrachloromethane; Irradiation;
DOI:10.1080/00304949809355262

Reference yield:

: 94348-18-2
2-Bromomethyl-6,6-dimethyl-3-oxo-cyclohex-1-enecarbonyl bromide

: 51799-97-4
Methyl-2-bromaethyl-6,6-dimethyl-3-oxocyclohex-1-en-1-carboxylat

Guidance literature:: In methanol; tetrachloromethane; at 0 ℃; for 6h; Yield given;
DOI:10.1021/jo00205a014

Reference yield:

: 60078-92-4,14393-38-5
2,4,4-trimethyl-3-formyl-2-cyclohexen-1-ol

: 51799-97-4
Methyl-2-bromaethyl-6,6-dimethyl-3-oxocyclohex-1-en-1-carboxylat

Guidance literature:: Multi-step reaction with 3 steps

1: 88 percent / Jones' reagent / acetone / 0.25 h / 0 °C

2: N-bromosuccinimide (NBS) / CCl₄ / 3 h / 70 °C / Irradiation

3: CCl₄; methanol / 6 h / 0 °C

With N-Bromosuccinimide; jones' reagent; In methanol; tetrachloromethane; acetone;
DOI:10.1021/jo00205a014