4-Methylbenzene-1-selenenyl chloride

Base Information

• Chemical Name: 4-Methylbenzene-1-selenenyl chloride
• CAS No.: 52178-47-9
• Molecular Formula: C7H7ClSe
• Molecular Weight: 205.546
• DSSTox Substance ID: DTXSID80506055
• Wikidata: Q82361615
• Mol file: 52178-47-9.mol

Synonyms:52178-47-9;4-Methylbenzene-1-selenenyl chloride;DTXSID80506055

Chemical Property of 4-Methylbenzene-1-selenenyl chloride

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 205.94015
• Heavy Atom Count: 9
• Complexity: 77

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)[Se]Cl

Technology Process of 4-Methylbenzene-1-selenenyl chloride

There total 3 articles about 4-Methylbenzene-1-selenenyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

di-p-tolyl diselenide (21856-94-0) → 4-methylphenylselenium chloride (52178-47-9)

Guidance literature:

With sulfuryl dichloride; In chloroform;

DOI:10.1139/v75-267

Reference yield:

p-tolyl selenocyanate (21856-93-9) → 4-methylphenylselenium chloride (52178-47-9)

Guidance literature:

With sulfuryl dichloride; In tetrachloromethane;

DOI:10.1021/jo00171a002

Reference yield:

p-toluidine (106-49-0,12221-03-3) → 4-methylphenylselenium chloride (52178-47-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 1) 20percent H₂SO₄, NaNO₂, NaOAc / 1) 4 deg C, 2) water, 48 h, r.t.

2: SO₂Cl₂ / CCl₄

With sulfuryl dichloride; sulfuric acid; sodium acetate; sodium nitrite; In tetrachloromethane;

DOI:10.1021/jo00171a002

upstream raw materials:

di-p-tolyl diselenide

p-tolyl selenocyanate

p-toluidine

Downstream raw materials:

β-(4-methylphenylseleno)ethyl chloride

C₁₄H₁₃Cl₂NOSe

1,2-dichloro-ethane

1-((E)-2-Chloro-vinylselanyl)-4-methyl-benzene