2,2,4,4-Tetra-tert-butyl-1,3,2,4-dithiadistannetane

Base Information

• Chemical Name: 2,2,4,4-Tetra-tert-butyl-1,3,2,4-dithiadistannetane
• CAS No.: 52196-01-7
• Molecular Formula: C₁₆H₃₆S₂Sn₂
• Molecular Weight: 530.014
• DSSTox Substance ID: DTXSID40586934
• Wikidata: Q82479159
• Mol file: 52196-01-7.mol

Synonyms:52196-01-7;SCHEMBL8029123;2,2,4,4-Tetra-tert-butyl-1,3,2,4-dithiadistannetane;DTXSID40586934

Chemical Property of 2,2,4,4-Tetra-tert-butyl-1,3,2,4-dithiadistannetane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 530.02965
• Heavy Atom Count: 20
• Complexity: 297

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)[Sn]1(S[Sn](S1)(C(C)(C)C)C(C)(C)C)C(C)(C)C

Technology Process of 2,2,4,4-Tetra-tert-butyl-1,3,2,4-dithiadistannetane

There total 1 articles about 2,2,4,4-Tetra-tert-butyl-1,3,2,4-dithiadistannetane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Cl((CH3)3C)2SnSClSn((CH3)3C)2Cl(1-)*((C6H5)3P)2N(1+)=[((C6H5)3P)2N][S(Sn(C4H9)2Cl)2Cl] (392730-67-5) → ((CH3)3C)2SnCl3(1-)*((C6H5)3P)2N(1+)=[((C6H5)3P)2N][(Sn(C4H9)2Cl3)] + (t-Bu2SnS)2 (52196-01-7)

Guidance literature:

In chloroform-d1; not isolated, detected by NMR;

DOI:10.1016/S0022-328X(01)01069-5

Reference yield:

bis(dichlorophenylstannyl)methane (92635-80-8) + (t-Bu2SnS)2 (52196-01-7) → ((C6H5Sn(S))2CH2)2 (148992-31-8)

Guidance literature:

In dichloromethane; the Sn-compds. were dissolved in CH2Cl2 and stirred for 10 min at room temp.; pptd. by addn. of ether;

DOI:10.1021/om00031a054

upstream raw materials:

Cl((CH₃)3C)2SnSClSn((CH₃)3C)2Cl^(1-)*((C₆H₅)3P)2N⁽¹⁺⁾=[((C₆H₅)3P)2N][S(Sn(C₄H₉)2Cl)2Cl]

Downstream raw materials:

((C₆H₅Sn(S))2CH₂)2