{[2-(Benzenesulfinyl)ethyl]sulfanyl}benzene

Base Information

• Chemical Name: {[2-(Benzenesulfinyl)ethyl]sulfanyl}benzene
• CAS No.: 53943-04-7
• Molecular Formula: C14H14OS2
• Molecular Weight: 262.397
• DSSTox Substance ID: DTXSID70491663
• Mol file: 53943-04-7.mol

Synonyms:53943-04-7;{[2-(Benzenesulfinyl)ethyl]sulfanyl}benzene;DTXSID70491663

Chemical Property of {[2-(Benzenesulfinyl)ethyl]sulfanyl}benzene

Chemical Property:

• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 262.04860741
• Heavy Atom Count: 17
• Complexity: 230

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)SCCS(=O)C2=CC=CC=C2

Technology Process of {[2-(Benzenesulfinyl)ethyl]sulfanyl}benzene

There total 2 articles about {[2-(Benzenesulfinyl)ethyl]sulfanyl}benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

Phenyl vinyl sulfoxide (20451-53-0) + thiophenol (108-98-5) → 1-phenylsulfinyl-2-phenylthioethane (53943-04-7)

Guidance literature:

With tetra(n-butyl)ammonium hydroxide; In ethanol; water; at 20 ℃; for 35h; Green chemistry;

DOI:10.1055/s-0033-1341106

Reference yield:

→ 1-phenylsulfinyl-2-phenylthioethane (53943-04-7)

Guidance literature:

Bissulfid IV, Ether, H2O2, Oxidation;

Reference yield: 83.0%

trans-dibromotetrakis(dimethyl sulfoxide)ruthenium(II) (72904-46-2) + 1-phenylsulfinyl-2-phenylthioethane (53943-04-7) → dibromobis(dimethyl sulphoxide)(1-phenylsulphinyl-2-phenyl-tioethane)ruthenium(II) (133922-96-0)

Guidance literature:

In ethanol; to a slurry of trans-(RuBr2(Ne2SO)4) was added 1-phenylsulphinyl-2-phenylthioethane with vigorous stirring, 2 d stirring at room temp.; filtration, washed with ethanol and diethyl ether; elem. anal.;

upstream raw materials:

Phenyl vinyl sulfoxide

thiophenol

Downstream raw materials:

1,2-bis-(phenylmercapto)ethylene

dibromobis(dimethyl sulphoxide)(1-phenylsulphinyl-2-phenyl-tioethane)ruthenium(II)