Phosphorane, triphenyl[3-(trimethylsilyl)-2-propynylidene]-

Base Information

Chemical Name:Phosphorane, triphenyl[3-(trimethylsilyl)-2-propynylidene]-
CAS No.:54541-88-7
Molecular Formula:C24H25PSi
Molecular Weight:372.51500
Hs Code.:
DSSTox Substance ID:DTXSID30454077
Nikkaji Number:J1.268.371E

Synonyms:54541-88-7;Phosphorane, triphenyl[3-(trimethylsilyl)-2-propynylidene]-;DTXSID30454077;1-(Trimethylsilyl)-3-(triphenylphosphoranylidene)-1-propyne

Suppliers and Price of Phosphorane, triphenyl[3-(trimethylsilyl)-2-propynylidene]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of Phosphorane, triphenyl[3-(trimethylsilyl)-2-propynylidene]-

Chemical Property:

PSA：9.81000
LogP:4.66350
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:4
Exact Mass:372.14631433
Heavy Atom Count:26
Complexity:500

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)C#CC=P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Phosphorane, triphenyl[3-(trimethylsilyl)-2-propynylidene]-

There total 1 articles about Phosphorane, triphenyl[3-(trimethylsilyl)-2-propynylidene]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 42134-49-6
(3-trimethylsilyl-2-propynyl)triphenylphosphonium bromide

: 54541-88-7
triphenyl(3-(trimethylsilyl)prop-2-yn-1-ylidene)-λ5-phosphane

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; at -78 - -40 ℃; Inert atmosphere;
DOI:10.1021/ol801921d

Reference yield:

: 54541-88-7
triphenyl(3-(trimethylsilyl)prop-2-yn-1-ylidene)-λ5-phosphane

: 5-((benzyloxy)methyl)-hexahydrofuro[3,2-b]furan-2-ol

: (2R,3R,5R)-5-Benzyloxymethyl-2-((Z)-pent-2-en-4-ynyl)-tetrahydro-furan-3-ol

: (2R,3R,5R)-5-Benzyloxymethyl-2-((E)-pent-2-en-4-ynyl)-tetrahydro-furan-3-ol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at -78 - 20 ℃; Title compound not separated from byproducts;
DOI:10.1002/(SICI)1521-3773(19991102)38:21<3175::AID-ANIE3175>3.0.CO;2-M