bis[2-(methylsulfanyl)phenyl](phenyl)phosphane

Base Information

• Chemical Name: bis[2-(methylsulfanyl)phenyl](phenyl)phosphane
• CAS No.: 14791-95-8
• Molecular Formula: C₂₀H₁₉PS₂
• Molecular Weight: 354.477

Synonyms:Phosphine,bis[o-(methylthio)phenyl]phenyl- (8CI);Bis[o-(methylthio)phenyl]phenylphosphine; NSC 310399

Chemical Property of bis[2-(methylsulfanyl)phenyl](phenyl)phosphane

Chemical Property:

• Vapor Pressure: 3.26E-08mmHg at 25°C
• Boiling Point: 460.2°Cat760mmHg
• Flash Point: 232.1°C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis[2-(methylsulfanyl)phenyl](phenyl)phosphane

There total 2 articles about bis[2-(methylsulfanyl)phenyl](phenyl)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(methylthio)iodobenzene (33775-94-9) + phenylphosphane (638-21-1) → bis-(2-methylthiophenyl)-phenylphosphine (14791-95-8) + phenyl tris(2-methylthiophenyl)phosphonium iodide

Guidance literature:

With 1,3-dicyano-5-fluoro-2,4,6-tris(diphenylamino)benzene; triethylamine; In acetonitrile; benzene; for 18h; Inert atmosphere; Glovebox; Sealed tube; Irradiation;

DOI:10.1002/chem.202002646

Reference yield:

→ bis-(2-methylthiophenyl)-phenylphosphine (14791-95-8)

Guidance literature:

o-Methylthioanilin (Iodanilin) 1)n-BuLi/PhPCl2 2)Hydrolyse;

DOI:10.1016/0020-1650(67)80118-1

Reference yield: 92.0%

sodium tetrachloropalladate(II) + bis-(2-methylthiophenyl)-phenylphosphine (14791-95-8) → Pd{bis{o-(methylthio)phenyl}phenylphosphino}Cl2 (18421-55-1,14876-88-1)

Guidance literature:

In dichloromethane; Reflux;

DOI:10.1002/ejoc.201501354

upstream raw materials:

2-(methylthio)iodobenzene

phenylphosphane

Downstream raw materials:

NiBr₂(Phenyl-bis-(2-methylmercapto-phenyl)-phosphin)

NiCl₂(Phenyl-bis-(2-methylmercapto-phenyl)-phosphin)

NiI₂(Phenyl-bis-(2-methylmercapto-phenyl)-phosphin)

Pd{bis{o-(methylthio)phenyl}phenylphosphino}Br₂

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