Methyl 4-(bromomethyl)thiophene-2-carboxylate

Base Information

Chemical Name:Methyl 4-(bromomethyl)thiophene-2-carboxylate
CAS No.:54796-51-9
Molecular Formula:C7H7BrO2S
Molecular Weight:235.101
Hs Code.:2934999090
DSSTox Substance ID:DTXSID30573055
Wikidata:Q82461634
Mol file:54796-51-9.mol

Synonyms:Methyl 4-(bromomethyl)thiophene-2-carboxylate;54796-51-9;2-Thiophenecarboxylic acid, 4-(bromomethyl)-, methyl ester;Methyl4-(bromomethyl)thiophene-2-carboxylate;SCHEMBL1401554;DTXSID30573055;KNBMDMSLFAPOSE-UHFFFAOYSA-N;AKOS016001560;EN300-226617;A870355;4-Bromomethyl-2-thiophenecarboxylic acid, methyl ester;4-bromomethyl-thiophene-2-carboxylic acid methyl ester

Suppliers and Price of Methyl 4-(bromomethyl)thiophene-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
Methyl4-(bromomethyl)thiophene-2-carboxylate 97%
1g
$ 365.00

Chemenu
methyl4-(bromomethyl)thiophene-2-carboxylate 97%
1g
$ 342.00

Arctom
Methyl4-(bromomethyl)thiophene-2-carboxylate 97%
1g
$ 145.00

Arctom
Methyl4-(bromomethyl)thiophene-2-carboxylate 97%
5g
$ 434.00

American Custom Chemicals Corporation
METHYL-4-(BROMOMETHYL)THIOPHENE-2-CARBOXYLATE 95.00%
5MG
$ 499.32

Alichem
Methyl4-(bromomethyl)thiophene-2-carboxylate
1g
$ 400.00

AK Scientific
Methyl4-(bromomethyl)thiophene-2-carboxylate
100mg
$ 548.00

Total 12 raw suppliers

Chemical Property of Methyl 4-(bromomethyl)thiophene-2-carboxylate

Chemical Property:

Boiling Point:304.6±32.0 °C(Predicted)
PSA：54.54000
Density:1.606±0.06 g/cm3(Predicted)
LogP:2.42960
Storage Temp.:Sealed in dry,Store in freezer, under -20°C
XLogP3:2.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:233.93501
Heavy Atom Count:11
Complexity:151

Purity/Quality:

97% ^*data from raw suppliers

Methyl4-(bromomethyl)thiophene-2-carboxylate 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=CC(=CS1)CBr

Technology Process of Methyl 4-(bromomethyl)thiophene-2-carboxylate

There total 5 articles about Methyl 4-(bromomethyl)thiophene-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 28686-90-0
4-methyl-thiophene-2-carboxylic acid methyl ester

: 54796-51-9
methyl 4-(bromomethyl)thiophene-2-carboxylate

Guidance literature:: With N-Bromosuccinimide; dibenzoyl peroxide; In tetrachloromethane; for 2h; Reflux;
DOI:10.1016/j.bmc.2012.08.009

Reference yield: 60.0%

: 816449-72-6
4-hydroxymethyl-thiophene-2-carboxylic acid methyl ester

: 54796-51-9
methyl 4-(bromomethyl)thiophene-2-carboxylate

Guidance literature:: 4-hydroxymethyl-thiophene-2-carboxylic acid methyl ester; With phosphorus tribromide; In tetrahydrofuran; at 25 ℃; for 1h;

With sodium hydrogencarbonate; In tetrahydrofuran; water;

Reference yield:

: 616-44-4,84928-92-7
3-Methylthiophene

: 79-22-1
methyl chloroformate

: 54796-51-9
methyl 4-(bromomethyl)thiophene-2-carboxylate

Guidance literature:: 3-Methylthiophene; With n-butyllithium; In tetrahydrofuran; at 0 ℃;

methyl chloroformate; In tetrahydrofuran; at 0 ℃; for 16h;

With N-Bromosuccinimide; dibenzoyl peroxide; In tetrachloromethane; for 17h; Reflux;
DOI:10.3390/molecules15053121