5-Phenyltetraphene-7,12-dione

Base Information

• Chemical Name: 5-Phenyltetraphene-7,12-dione
• CAS No.: 54988-91-9
• Molecular Formula: C24H14O2
• Molecular Weight: 334.374
• DSSTox Substance ID: DTXSID80488140
• Nikkaji Number: J324.902F
• Wikidata: Q82330596
• Mol file: 54988-91-9.mol

Synonyms:54988-91-9;5-Phenyltetraphene-7,12-dione;DTXSID80488140

Chemical Property of 5-Phenyltetraphene-7,12-dione

Chemical Property:

• XLogP3: 5.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 334.099379685
• Heavy Atom Count: 26
• Complexity: 561

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC3=C(C4=CC=CC=C42)C(=O)C5=CC=CC=C5C3=O

Technology Process of 5-Phenyltetraphene-7,12-dione

There total 12 articles about 5-Phenyltetraphene-7,12-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

2,3-Dichloro-1,4-naphthoquinone (117-80-6) + 1,1-Diphenylethylene (530-48-3) → 5-phenylbenzanthracene-7,12-dione (54988-91-9) + 1,6-dichloro-8,8-diphenyl-3,4-benzobicyclo<4.2.0>oct-3-ene-2,5-dione (93403-98-6)

Guidance literature:

With pyridine; In benzene; for 70h; Ambient temperature; Irradiation;

DOI:10.1021/jo00201a011

Reference yield: 49.0%

1,1-Diphenylethylene (530-48-3) + 2-bromo-3-methoxy-1,4-naphthoquinone (26037-61-6) → 5-phenylbenzanthracene-7,12-dione (54988-91-9)

Guidance literature:

With pyridine; In benzene; for 3.5h; Ambient temperature; Irradiation;

DOI:10.1021/jo00201a011

Reference yield: 49.0%

C24H16O → 5-phenylbenzanthracene-7,12-dione (54988-91-9)

Guidance literature:

With sodium hydrogencarbonate; Selectfluor; In acetonitrile; at 20 ℃;

DOI:10.1039/c9cc08628e

upstream raw materials:

2,3-Dichloro-1,4-naphthoquinone

1,1-Diphenylethylene

2-bromo-1,4-naphthoquinone

2-bromo-3-methoxy-1,4-naphthoquinone

Downstream raw materials:

methyl 4-phenyl-2-naphthoate

5-phenyltetraphene