2-Methyl-2-dodecene

Base Information

• Chemical Name: 2-Methyl-2-dodecene
• CAS No.: 55103-82-7
• Molecular Formula: C13H26
• Molecular Weight: 182.349
• Hs Code.: 2901299090
• Mol file: 55103-82-7.mol

Synonyms:2-methyl-dodec-2-ene;2-Methyl-2-dodecene;2-Dodecene,2-methyl;

Chemical Property of 2-Methyl-2-dodecene

Chemical Property:

• PSA: 0.00000
• LogP: 5.09330

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Methyl-2-dodecene

There total 10 articles about 2-Methyl-2-dodecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

methyl-2 dodecanol-2 (1653-37-8) → 2-methyl-2-dodecene (55103-82-7)

Guidance literature:

With Amberlyst-15; In dichloromethane; at 20 ℃; for 3h;

DOI:10.1016/j.tet.2012.06.083

Reference yield: 67.0%

1-(isopropylsulfonyl)-3,5-bis(trifluoromethyl)benzene (917481-50-6) + caprinaldehyde (112-31-2) → 2-methyl-2-dodecene (55103-82-7)

Guidance literature:

With phosphazene base-P₄-tert-butyl; In tetrahydrofuran; hexane; at 20 ℃;

DOI:10.1002/ejoc.200600478

Reference yield: 20.0%

tert-butyl 1-(2-methylbut-3-en-2-yl)-2-octylidenehydrazine-1-carboxylate → 2-methyl-2-dodecene (55103-82-7)

Guidance literature:

With bis(trifluoromethanesulfonyl)amide; In diethylene glycol dimethyl ether; at 125 ℃; for 1.25h; Schlenk technique; Inert atmosphere;

DOI:10.1002/ejoc.202000382

upstream raw materials:

1-tridecene

1-Decene

2-(isopropylsulfonyl)-2-methylpropane

1-dodecene

Downstream raw materials:

N-(2-methyldodec-2-yl)benzamide

Refernces

• 1、 Frija, Luís M.T.,Afonso, Carlos A.M.. "Amberlyst-15: A reusable heterogeneous catalyst for the dehydration of tertiary alcohols". . p. 7414 - 7421. Retrieved 2012/09/22.
• 2、 Tanaka, Hirotaka,Hashimoto, Kentaro,Suzuki, Kyosuke,Kitaichi, Yasunori,Sato, Mitsuo,Ikeno, Taketo,Yamada, Tohru. "Nitrous oxide oxidation catalyzed by ruthenium porphyrin complex". . p. 1905 - 1914. Retrieved 2007/10/03.