Lithium 1-(trimethylsilyl)-1H-inden-1-ide

Base Information

Chemical Name:Lithium 1-(trimethylsilyl)-1H-inden-1-ide
CAS No.:55563-48-9
Molecular Formula:C12H15LiSi
Molecular Weight:194.278
Hs Code.:
DSSTox Substance ID:DTXSID20558270

Synonyms:55563-48-9;Lithium 1-(trimethylsilyl)-1H-inden-1-ide;DTXSID20558270

Suppliers and Price of Lithium 1-(trimethylsilyl)-1H-inden-1-ide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Lithium 1-(trimethylsilyl)-1H-inden-1-ide

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:194.11030545
Heavy Atom Count:14
Complexity:185

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[Li+].C[Si](C)(C)[C-]1C=CC2=CC=CC=C12

Technology Process of Lithium 1-(trimethylsilyl)-1H-inden-1-ide

There total 1 articles about Lithium 1-(trimethylsilyl)-1H-inden-1-ide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 18053-75-3
3-Trimethylsilylinden

: 55563-48-9
{1-(trimethylsilyl)indenyl}lithium

Guidance literature:: With n-butyllithium; In hexane;

Reference yield: 77.0%

: 14264-16-5,53996-95-5,62075-39-2,39716-73-9
bis(triphenylphosphine)nickel(II) chloride

: 55563-48-9
{1-(trimethylsilyl)indenyl}lithium

: 833483-55-9,329359-88-8
[(1-SiMe₃-indenyl)Ni(PPh₃)Cl]

Guidance literature:: In diethyl ether; (N2); standard Schlenk technique; soln. of Li salt of ligand in Et2O wasadded dropwise to stirred suspn. of Ni complex in Et2O at room temp.; m ixt. was stirred for 20 min; filtered; filtrate evapd. (vac.); washed (hexane); extd. (ether/hexane, 1/5); evapd.; elem. anal.;
DOI:10.1021/om0494420

Reference yield:

: 55563-48-9
indenyl(SiMe₃)lithium

: Bis(pentafluorophenyl)boronfluoride diethyl ether complex

: 197009-66-8
(C₆H₄CHCHC(SiMe₃))(pentafluorophenyl)2B

: 197009-56-6
(C₆H₄CH(SiMe₃)CHC)(pentafluorophenyl)2B

Guidance literature:: In diethyl ether; N2-atmosphere; equimolar amts., addn. of indenyllithium to soln. of B-compound at -78°C, warming to room temp., stirring for 4 h; evapn., extn. (light petroleum, 40°C), evapn., crystn. on cooling; isomers not sepd., overall yield 47%; elem. anal.;
DOI:10.1021/om970433j