Hexamethylsilirane

Base Information

• Chemical Name: Hexamethylsilirane
• CAS No.: 55644-09-2
• Molecular Formula: C8H18Si
• Molecular Weight: 142.316
• DSSTox Substance ID: DTXSID90498437
• Nikkaji Number: J715.962E
• Wikidata: Q82348481
• Mol file: 55644-09-2.mol

Synonyms:Hexamethylsilirane;55644-09-2;hexamethyl-1-silacyclopropane;DTXSID90498437

Chemical Property of Hexamethylsilirane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 142.117777109
• Heavy Atom Count: 9
• Complexity: 127

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1(C([Si]1(C)C)(C)C)C

Technology Process of Hexamethylsilirane

There total 2 articles about Hexamethylsilirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

octamethyl-1,2-disilacyclobutane (62346-42-3) → 2,3-Dimethyl-2-butene (563-79-1) + hexamethylsilirane (55644-09-2)

Guidance literature:

for 0.5h; Mechanism; Ambient temperature; Irradiation;

DOI:10.1016/S0022-328X(00)93422-3

Reference yield:

2,3-Dimethyl-2-butene (563-79-1) + dibenzo-1,1,2,2-tetramethyl-1,2-disilacyclohexa-3,5-diene (85590-07-4) → 9,9-dimethyl-9-silafluorene (13688-68-1) + hexamethylsilirane (55644-09-2)

Guidance literature:

In benzene; for 5h; Irradiation;

DOI:10.1021/ja00363a058

Reference yield: 90.0%

hexamethylsilirane (55644-09-2) → chlorodimethyl(1,1,2-trimethylpropyl)silane (67373-56-2)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; Ambient temperature;

DOI:10.1016/S0022-328X(00)86821-7

upstream raw materials:

2,3-Dimethyl-2-butene

dibenzo-1,1,2,2-tetramethyl-1,2-disilacyclohexa-3,5-diene

octamethyl-1,2-disilacyclobutane

Downstream raw materials:

[Dimethyl-(1,1,2-trimethyl-propyl)-silanyl]-methyl-phosphane

1,1,2,3,3-Pentamethyl-1,3-bis-(1,1,2-trimethyl-propyl)-disilaphosphane

[Dimethyl-(1,1,2-trimethyl-propyl)-silanyl]-diphenyl-phosphane

2,2,3,3,4,4,5,5-octamethyl-1-oxa-2,5-disilacyclopentane