Pentasilane, 1,5-dichloro-1,1,2,2,3,3,4,4,5,5-decamethyl-

Base Information

• Chemical Name: Pentasilane, 1,5-dichloro-1,1,2,2,3,3,4,4,5,5-decamethyl-
• CAS No.: 5586-42-5
• Molecular Formula: C10H30Cl2Si5
• Molecular Weight: 361.682
• DSSTox Substance ID: DTXSID20454066
• Nikkaji Number: J961.528H
• Wikidata: Q82275399

Synonyms:5586-42-5;Pentasilane, 1,5-dichloro-1,1,2,2,3,3,4,4,5,5-decamethyl-;1,5-Dichlorodecamethylpentasilane;1,5-Dichlordecamethylpentasilan;bis[[chloro(dimethyl)silyl]-dimethylsilyl]-dimethylsilane;DTXSID20454066

Chemical Property of Pentasilane, 1,5-dichloro-1,1,2,2,3,3,4,4,5,5-decamethyl-

Chemical Property:

• PSA: 0.00000
• LogP: 5.31300
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 360.0570890
• Heavy Atom Count: 17
• Complexity: 269

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)([Si](C)(C)[Si](C)(C)Cl)[Si](C)(C)[Si](C)(C)Cl

Technology Process of Pentasilane, 1,5-dichloro-1,1,2,2,3,3,4,4,5,5-decamethyl-

There total 4 articles about Pentasilane, 1,5-dichloro-1,1,2,2,3,3,4,4,5,5-decamethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.1%

polydimethylsilane → 1,3-dichloro-1,1,2,2,3,3-hexamethyltrisilane (812-36-2) + 1,2-dichlorotetramethylsilane (4342-61-4) + 1,4-dichloropermethyltetrasilane (754-75-6) + 1,5-dichlorodecamethylpentasilane (5586-42-5)

Guidance literature:

With tin(IV) chloride; at 180 ℃; for 3h; Further Variations:; Reagents; Temperatures; reaction times; Product distribution;

DOI:10.1023/A:1021376210839

Reference yield: 10.0%

dodecamethylcyclohexasilane (4098-30-0) → 1,3-dichloro-1,1,2,2,3,3-hexamethyltrisilane (812-36-2) + 1,2-dichlorotetramethylsilane (4342-61-4) + 1,4-dichloropermethyltetrasilane (754-75-6) + 1,5-dichlorodecamethylpentasilane (5586-42-5)

Guidance literature:

With tin(IV) chloride; at 175 ℃; for 1h; Further Variations:; Reagents; Temperatures; reaction times; Product distribution;

DOI:10.1023/A:1015094621119

Reference yield:

dodecamethylcyclohexasilane (4098-30-0) → 1,3-dichloro-1,1,2,2,3,3-hexamethyltrisilane (812-36-2) + 1,2-dichlorotetramethylsilane (4342-61-4) + 1,4-dichloropermethyltetrasilane (754-75-6) + 1,5-dichlorodecamethylpentasilane (5586-42-5) + 1,2-Dichloro-1,2,3,3,4,4,5,5,6,6-decamethyl-hexasilinane

Guidance literature:

With chlorine; In tetrachloromethane; also chlorination of 1,4-Cl₂Si₄Me₈;

DOI:10.1016/0022-328X(83)80238-1

upstream raw materials:

dodecamethylcyclohexasilane

1,2-dichlorotetramethylsilane

Downstream raw materials:

1,5-Bis-(pentachlor-phenyl)-decamethyl-pentasilan

1,2,2,3,3,4,4,5,5,6,6-Undecamethyl-[1,2,3,4,5,6]phosphapentasilinane

1,5-bis(4-(methylthio)phenyl)decamethylpentasilane

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