Tris(3,5-diphenylphenyl)phosphane

Base Information

Chemical Name:Tris(3,5-diphenylphenyl)phosphane
CAS No.:561068-06-2
Molecular Formula:C54H39P
Molecular Weight:718.877
Hs Code.:
DSSTox Substance ID:DTXSID60514517
Nikkaji Number:J1.896.272A
Wikidata:Q82374892

Synonyms:561068-06-2;DTXSID60514517;Tri([1~1~,2~1~:2~3~,3~1~-terphenyl]-2~5~-yl)phosphane

Suppliers and Price of Tris(3,5-diphenylphenyl)phosphane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Tris(3,5-diphenylphenyl)phosphane

Chemical Property:

XLogP3:14.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:9
Exact Mass:718.278938242
Heavy Atom Count:55
Complexity:876

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)C2=CC(=CC(=C2)P(C3=CC(=CC(=C3)C4=CC=CC=C4)C5=CC=CC=C5)C6=CC(=CC(=C6)C7=CC=CC=C7)C8=CC=CC=C8)C9=CC=CC=C9

Technology Process of Tris(3,5-diphenylphenyl)phosphane

There total 1 articles about Tris(3,5-diphenylphenyl)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 103068-20-8
1-bromo-3,5-diphenylbenzene

: 561068-06-2
tris(m-terphenyl-5'-yl)phosphane

Guidance literature:: 1-bromo-3,5-diphenylbenzene; With magnesium; In tetrahydrofuran;

With phosphorus trichloride; In tetrahydrofuran; for 12h; Heating;
DOI:10.1055/s-2004-831168

Reference yield:

: chlorobis(ethylene)rhodium(I) dimer

: 561068-06-2
tris(m-terphenyl-5'-yl)phosphane

: [RhCl(C₂H₄)2(P(C₆H₃(C₆H₅)2)3)]

: 2Rh⁽¹⁺⁾*4P(C₆H₃(C₆H₅)2)3*2Cl^(1-)=[(RhCl(P(C₆H₃(C₆H₅)2)3)2)2]

Guidance literature:: In benzene-d6; Rh complex and phosphine mixed at room temp.; P/Rh ratio = 1:1 and 2:1; not isolated, detected by 31P-NMR spectroscopy;
DOI:10.1021/om0503491

Reference yield:

: chlorobis(ethylene)rhodium(I) dimer

: 561068-06-2
tris(m-terphenyl-5'-yl)phosphane

: 2Rh⁽¹⁺⁾*4P(C₆H₃(C₆H₅)2)3*2Cl^(1-)=[(RhCl(P(C₆H₃(C₆H₅)2)3)2)2]

: [RhCl(P(C₆H₃(C₆H₅)2)3)3]

Guidance literature:: In benzene-d6; Rh complex and phosphine mixed at room temp.; P/Rh ratio = 3:1; not isolated, detected by 31P-NMR spectroscopy and MS;
DOI:10.1021/om0503491