Magnesium, bromohexyl-

Base Information

• Chemical Name: Magnesium, bromohexyl-
• CAS No.: 3761-92-0
• Molecular Formula: C6H13BrMg
• Molecular Weight: 189.378
• Hs Code.: 29319090
• European Community (EC) Number: 684-549-7
• DSSTox Substance ID: DTXSID70884011
• Mol file: 3761-92-0.mol

Synonyms:Hexylmagnesium Bromide;3761-92-0;Magnesium, bromohexyl-;magnesium;hexane;bromide;n-hexylmagnesium bromide;MFCD00000046;Hexylmagnesium Bromide (20% in Tetrahydrofuran, ca. 1mol/L);n-HexMgBr;Bromohexyl magnesium;hexyl magnesium bromide;C6H13BrMg;n-hexyl magnesium bromide;C6-H13-Br-Mg;SCHEMBL153016;DTXSID70884011;SFXUWNMDTWQSHE-UHFFFAOYSA-M;AKOS015903399;Hexylmagnesium bromide, 1.0 M in THF;Hexylmagnesium bromide, 1.0 M in 2-MeTHF;J-802223;HEXYLMAGNESIUM BROMIDE SOL. 2.0 M IN DIETHYL ETHER

Chemical Property of Magnesium, bromohexyl-

Chemical Property:

• Appearance/Colour: Brown solution
• Flash Point: -40 °C
• PSA: 0.00000
• Density: 0.97 g/mL at 20 °C
• LogP: 3.37990
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 188.00510
• Heavy Atom Count: 8
• Complexity: 24.5

Purity/Quality:

98%,99%, ^*data from raw suppliers

HexylmagnesiumBromide,0.8MsolutioninTHF ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F+, C
• Hazard Codes: F+,C,F
• Statements: 12-14-22-34-66-67-19-11
• Safety Statements: 16-26-36/37/39-43-45-7/8-33-29-8

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCC[CH2-].[Mg+2].[Br-]

Technology Process of Magnesium, bromohexyl-

There total 2 articles about Magnesium, bromohexyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-bromo-hexane (111-25-1) → n-hexylmagnesium bromide (3761-92-0)

Guidance literature:

With magnesium; In diethyl ether; Thermodynamic data; -ΔH(reaction);

Reference yield:

→ n-hexylmagnesium bromide (3761-92-0)

Guidance literature:

Reference yield: 95.6%

3-Bromothiophene (872-31-1) + n-hexylmagnesium bromide (3761-92-0) → 3-hexylthiophene (1693-86-3)

Guidance literature:

1,3-bis[(diphenylphosphino)propane]dichloronickel(II); In diethyl ether; at 0 - 20 ℃; Inert atmosphere;

upstream raw materials:

1-bromo-hexane

Downstream raw materials:

octanol

2,3-dimethylnonane

(E)-2-Nonenal

methyltri(hexyl)silane

Refernces

• 1、 Lee, Sun-Young,Jung, Choong-Hwa,Kang, Jun,Kim, Hee-Joon,Shin, Won Suk,Yoon, Sung Cheol,Moon, Sang-Jin,Lee, Changjin,Hwang, Do-Hoon. "Synthesis of a new conjugated polymer composed of pyrene and bithiophene units for organic solar cells". experimental part. p. 4367 - 4372. Retrieved 2012/06/16.
• 2、 Holm, Torkil. "Thermochemical Bond Dissociation Energies of Carbon-Magnesium Bonds". . p. 464 - 467. Retrieved 2007/10/02.