Tri-tert-butylchlorosilane

Base Information

• Chemical Name: Tri-tert-butylchlorosilane
• CAS No.: 56348-24-4
• Molecular Formula: C12H27ClSi
• Molecular Weight: 234.885
• DSSTox Substance ID: DTXSID60499193
• Nikkaji Number: J2.130.018G
• Wikidata: Q82349758
• Mol file: 56348-24-4.mol

Synonyms:tri-tert-butylchlorosilane;56348-24-4;tri-t-butylchlorosilane;Tri-tert-butyl(chloro)silane;SCHEMBL708605;DTXSID60499193

Chemical Property of Tri-tert-butylchlorosilane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 234.1570551
• Heavy Atom Count: 14
• Complexity: 164

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(C)(C)[Si](C(C)(C)C)(C(C)(C)C)Cl

Technology Process of Tri-tert-butylchlorosilane

There total 1 articles about Tri-tert-butylchlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5,5-Di-tert-butyl-1-(di-tert-butylchlorsilyl)-4-(tri-tert-butylsilyl)-1,2,3,4-tetraaza-5-sila-2-cyclopenten (111470-27-0) → Di-tert-butyldichlorosilane (18395-90-9) + tBu3SiCl (56348-24-4) + Azido-chloro-di-tert-butylsilan (104957-97-3)

Guidance literature:

With hydrogenchloride; In benzene-d6; for 240h; Title compound not separated from byproducts;

DOI:10.1016/j.jorganchem.2005.04.057

Reference yield: 75.0%

tBu3SiCl (56348-24-4) + phenylacetylene (536-74-3) → phenyl(tri-tert-butylsilyl)acetylene

Guidance literature:

With zinc trifluoromethanesulfonate; triethylamine; In dichloromethane; at 30 ℃; for 15h;

DOI:10.1016/j.tetlet.2004.10.175

Reference yield: 66.0%

tBu3SiCl (56348-24-4) → 8-(tert-butyl-dimethyl-silanyloxy)-4-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1,3a,4,9b-tetrahydro-3H-cyclopenta[c]chromen-2-one

Guidance literature:

8-benzyloxy-4-(4-benzyloxy-phenyl)-1,3a,4,9b-tetrahydro-3H-cyclopenta[c]chromen-2-one; With hydrogen; palladium 10% on activated carbon; In tetrahydrofuran; isopropyl alcohol; under 3102.97 Torr;

tBu₃SiCl; With 1H-imidazole; dmap; In DMF (N,N-dimethyl-formamide);

upstream raw materials:

5,5-Di-tert-butyl-1-(di-tert-butylchlorsilyl)-4-(tri-tert-butylsilyl)-1,2,3,4-tetraaza-5-sila-2-cyclopenten

Downstream raw materials:

C₆₂H₁₁₄N₆O₂₅Si