2-Bromomethyl-terephthalic acid dimethyl ester

Base Information

Chemical Name:2-Bromomethyl-terephthalic acid dimethyl ester
CAS No.:57834-13-6
Molecular Formula:C11H11BrO4
Molecular Weight:287.10700
Hs Code.:
European Community (EC) Number:826-034-3
DSSTox Substance ID:DTXSID20604968
Nikkaji Number:J3.260.623G
Wikidata:Q82503058
Mol file:57834-13-6.mol

Synonyms:57834-13-6;2-BROMOMETHYL-TEREPHTHALIC ACID DIMETHYL ESTER;DIMETHYL 2-(BROMOMETHYL)TEREPHTHALATE;Dimethyl 2-(bromomethyl)benzene-1,4-dicarboxylate;1,4-Benzenedicarboxylic acid, 2-(bromomethyl)-, 1,4-dimethyl ester;1,4-Benzenedicarboxylic acid, 2-(bromomethyl)-, dimethyl ester;2-(Bromomethyl)terephthalic acid dimethyl ester;YSCH0167;SCHEMBL11601201;DTXSID20604968;UTIKNGRWJJKNBJ-UHFFFAOYSA-N;dimethyl-2-bromomethylterephthalate;dimethyl -2-bromomethylterephthalate;MFCD18251142;AKOS028114253;AB74313;AS-48099;DB-091401;dimethyl 2-(bromomethyl)benzene-1,4-dioate;CS-0159601;F18080;2-BROMOMETHYL-TEREPHTHALICACIDDIMETHYLESTER;1,4-dimethyl 2-(bromomethyl)benzene-1,4-dicarboxylate;2-(Bromomethyl)-1,4-benzenedicarboxylic acid 1,4-dimethyl ester

Suppliers and Price of 2-Bromomethyl-terephthalic acid dimethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

J&W Pharmlab
2-Bromomethyl-terephthalicaciddimethylester 97%
5g
$ 895.00

J&W Pharmlab
2-Bromomethyl-terephthalicaciddimethylester 97%
100mg
$ 123.00

Total 10 raw suppliers

Chemical Property of 2-Bromomethyl-terephthalic acid dimethyl ester

Chemical Property:

Boiling Point:381.4±37.0 °C(Predicted)
PSA：52.60000
Density:1.474±0.06 g/cm3(Predicted)
LogP:2.15470
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
XLogP3:2.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:5
Exact Mass:285.98407
Heavy Atom Count:16
Complexity:267

Purity/Quality:

99%, ^*data from raw suppliers

2-Bromomethyl-terephthalicaciddimethylester 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=CC(=C(C=C1)C(=O)OC)CBr

Technology Process of 2-Bromomethyl-terephthalic acid dimethyl ester

There total 2 articles about 2-Bromomethyl-terephthalic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 14186-60-8
2-Methyl-1,4-benzoldicarbonsaeure dimethylester

: 57834-13-6
2-bromomethyl-1,4-terephthalic acid dimethyl ester

Guidance literature:: With N-Bromosuccinimide; dibenzoyl peroxide; In tetrachloromethane; at 77 ℃; for 3h; Temperature;

Reference yield:

: 5156-01-4
2-methylterephthalic acid

: 57834-13-6
2-bromomethyl-1,4-terephthalic acid dimethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: sulfuric acid / 48 h / Reflux

2: N-Bromosuccinimide; dibenzoyl peroxide / tetrachloromethane / 5 h / 70 °C / Inert atmosphere

With N-Bromosuccinimide; sulfuric acid; dibenzoyl peroxide; In tetrachloromethane;