Benzenamine, 2-(diphenylphosphino)-N-[2-(diphenylphosphino)phenyl]-

Base Information

• Chemical Name: Benzenamine, 2-(diphenylphosphino)-N-[2-(diphenylphosphino)phenyl]-
• CAS No.: 579490-49-6
• Molecular Formula: C36H29NP2
• Molecular Weight: 537.58
• DSSTox Substance ID: DTXSID60466401
• Nikkaji Number: J1.926.493I
• Wikidata: Q82292955
• Mol file: 579490-49-6.mol

Synonyms:579490-49-6;Benzenamine, 2-(diphenylphosphino)-N-[2-(diphenylphosphino)phenyl]-;Bis(2-(diphenylphosphino)phenyl)amine;2-diphenylphosphanyl-N-(2-diphenylphosphanylphenyl)aniline;SCHEMBL2044796;DTXSID60466401;NAZDLMABXHCSPQ-UHFFFAOYSA-N;bis(2-diphenylphosphinophenyl)amine;bis[(2-diphenylphosphino)phenyl]amine

Chemical Property of Benzenamine, 2-(diphenylphosphino)-N-[2-(diphenylphosphino)phenyl]-

Chemical Property:

• XLogP3: 8.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 8
• Exact Mass: 537.17752392
• Heavy Atom Count: 39
• Complexity: 594

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3NC4=CC=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6

Technology Process of Benzenamine, 2-(diphenylphosphino)-N-[2-(diphenylphosphino)phenyl]-

There total 3 articles about Benzenamine, 2-(diphenylphosphino)-N-[2-(diphenylphosphino)phenyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.15%

N,N-bis(2-fluorophenyl)amine (328-15-4) + potassium diphenylphosphine (15475-27-1,4346-39-8) → 2,2'-bis(diphenylphosphino)diphenylamine (579490-49-6)

Guidance literature:

In 1,4-dioxane; for 48h; Heating / reflux;

Reference yield: 48.3%

2,2’-dibromodiphenylamine (67242-17-5) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → 2,2'-bis(diphenylphosphino)diphenylamine (579490-49-6)

Guidance literature:

2,2’-dibromodiphenylamine; With n-butyllithium; In diethyl ether; hexane; at 0 ℃; for 1.5h;

chloro-diphenylphosphine; In diethyl ether; hexane; at 0 - 20 ℃;

DOI:10.1016/S0022-328X(03)00776-9

Reference yield:

→ 2,2'-bis(diphenylphosphino)diphenylamine (579490-49-6)

Guidance literature:

upstream raw materials:

2,2’-dibromodiphenylamine

chloro-diphenylphosphine

N,N-bis(2-fluorophenyl)amine

potassium diphenylphosphine

Downstream raw materials:

[N(o-C₆H₄PPh₂)2]Ni(n-hexyl)

[N(o-C₆H₄PPh₂)2]NiH

[((((C₆H₅)2P)C₆H₄)2N)Lu(CH₂Si(CH₃)3)2(OC₄H₈)]

bis(diphenylphosphinophenyl)amido platinum(II) chloride