Benzenesulfonamide, N-(1-cyclohexen-1-ylmethyl)-4-methyl-

Base Information

Chemical Name:Benzenesulfonamide, N-(1-cyclohexen-1-ylmethyl)-4-methyl-
CAS No.:57981-23-4
Molecular Formula:C14H19NO2S
Molecular Weight:265.376
Hs Code.:
DSSTox Substance ID:DTXSID90443821
Nikkaji Number:J764.856A
Wikidata:Q82261779

Synonyms:Benzenesulfonamide, N-(1-cyclohexen-1-ylmethyl)-4-methyl-;DTXSID90443821;STL366668;AKOS025246702;57981-23-4;N-[(1-Cyclohexenyl)methyl]-4-methylbenzenesulfonamide;N-(cyclohex-1-en-1-ylmethyl)-4-methylbenzenesulfonamide

Suppliers and Price of Benzenesulfonamide, N-(1-cyclohexen-1-ylmethyl)-4-methyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzenesulfonamide, N-(1-cyclohexen-1-ylmethyl)-4-methyl-

Chemical Property:

XLogP3:2.8
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:265.11365002
Heavy Atom Count:18
Complexity:387

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)(=O)NCC2=CCCCC2

Technology Process of Benzenesulfonamide, N-(1-cyclohexen-1-ylmethyl)-4-methyl-

There total 9 articles about Benzenesulfonamide, N-(1-cyclohexen-1-ylmethyl)-4-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 191595-69-4
N-tosyl-S-phenyl-S-(1-cyclohex-1-enylmethyl)sulfoximine

: 57981-23-4
N-(cyclohex-1-en-1-ylmethyl)-4-methylbenzenesulfonamide

Guidance literature:: tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; for 0.166667h; Ambient temperature;
DOI:10.1021/jo9605105

Reference yield:

: 42153-74-2
S-methyl-S-phenyl-N-(p-tolylsulfonyl)sulfoximide

: 57981-23-4
N-(cyclohex-1-en-1-ylmethyl)-4-methylbenzenesulfonamide

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) n-BuLi / 1.) THF, -78 deg C, 40 min, 2.) -78 deg C, 1 h

2: 1.) Et₃N, methanesulfonyl chloride, 2.) DBU / 1.) CH₂Cl₂, 0 deg C, 2 h, 2.) 0 deg C, 10 min then room temperature overnight

3: 89 percent / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran / 0.17 h / Ambient temperature

With n-butyllithium; methanesulfonyl chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran;
DOI:10.1021/jo9605105

Reference yield:

: 1-(N-tosyl-S-phenylsulfonimidoyl)methylcyclohexanol

: 57981-23-4
N-(cyclohex-1-en-1-ylmethyl)-4-methylbenzenesulfonamide

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) Et₃N, methanesulfonyl chloride, 2.) DBU / 1.) CH₂Cl₂, 0 deg C, 2 h, 2.) 0 deg C, 10 min then room temperature overnight

2: 89 percent / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran / 0.17 h / Ambient temperature

With methanesulfonyl chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran;
DOI:10.1021/jo9605105