Technology Process of [(2R,3R)-3-methyloxiran-2-yl]methanol
There total 7 articles about [(2R,3R)-3-methyloxiran-2-yl]methanol which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
titanium(IV) isopropylate; D-(-)-diisopropyl tartrate;
In
dichloromethane;
at 300 ℃;
for 1.08333h;
Inert atmosphere;
Molecular sieve;
DOI:10.1002/anie.201410371
- Guidance literature:
-
(E)-but-2-enol;
With
titanium(IV) isopropylate; D-(-)-diisopropyl tartrate;
In
dichloromethane;
for 0.666667h;
Molecular sieve;
Cooling;
With
tert.-butylhydroperoxide;
In
dichloromethane; toluene;
for 3.33h;
enantioselective reaction;
Molecular sieve;
Cooling;
DOI:10.1039/c3ra47775d
- Guidance literature:
-
With
L-(+)-diisopropyl tartrate; dihydrogen peroxide;
titanium-pillared montmorillonite catalyst (Ti-PILC);
In
dichloromethane;
at -20 - -15 ℃;
for 4.2h;
Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1039/c39900001186
