2-Oxa-3-azabicyclo[2.2.1]hept-5-ene, 3-(3,5-dinitrobenzoyl)-

Base Information

Chemical Name:2-Oxa-3-azabicyclo[2.2.1]hept-5-ene, 3-(3,5-dinitrobenzoyl)-
CAS No.:59438-64-1
Molecular Formula:C12H9N3O6
Molecular Weight:
Hs Code.:
DSSTox Substance ID:DTXSID20483215

Synonyms:59438-64-1;2-Oxa-3-azabicyclo[2.2.1]hept-5-ene, 3-(3,5-dinitrobenzoyl)-;DTXSID20483215

Suppliers and Price of 2-Oxa-3-azabicyclo[2.2.1]hept-5-ene, 3-(3,5-dinitrobenzoyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 2-Oxa-3-azabicyclo[2.2.1]hept-5-ene, 3-(3,5-dinitrobenzoyl)-

Chemical Property:

XLogP3:1.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:1
Exact Mass:291.04913502
Heavy Atom Count:21
Complexity:488

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C2C=CC1ON2C(=O)C3=CC(=CC(=C3)[N+](=O)[O-])[N+](=O)[O-]

Technology Process of 2-Oxa-3-azabicyclo[2.2.1]hept-5-ene, 3-(3,5-dinitrobenzoyl)-

There total 1 articles about 2-Oxa-3-azabicyclo[2.2.1]hept-5-ene, 3-(3,5-dinitrobenzoyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 29882-36-8
N-hydroxy-3,5-dinitro-benzamide

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 59438-64-1
(+/-)-3-(3,5-dinitrobenzoyl)-2-oxa-3-azabicyclo<2.2.1>hept-5-ene

Guidance literature:: With benzyltrimethylammonium periodate;

Reference yield:

: 59438-64-1
(+/-)-3-(3,5-dinitrobenzoyl)-2-oxa-3-azabicyclo<2.2.1>hept-5-ene

: (+/-)-exo-cis-3-(3,5-dinitrobenzoyl)-5,6-O-isopropylidene-2-oxa-3-azabicyclo<2.2.1>heptane-5,6-diol

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) N-methylmorpholine N-oxide monohydrate, OsO₄; 2.) NaHSO₃ / 1.) acetone, H₂O, t-BuOH, r.t., 2 d; 2.) H₂O, r.t., 2 h

2: 94 percent / p-TsOH monohydrate / CH₂Cl₂ / 48 h / Heating

With osmium(VIII) oxide; toluene-4-sulfonic acid; sodium hydrogensulfite; 4-methylmorpholine N-oxide; In dichloromethane;
DOI:10.1002/hlca.19830660702

Reference yield:

: 59438-64-1
(+/-)-3-(3,5-dinitrobenzoyl)-2-oxa-3-azabicyclo<2.2.1>hept-5-ene

: (+/-)-1β-(benzyloxycarbonylamino)-2α,3α-O-isopropylidene-2α,3α,4β-cyclopentanetriol

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) N-methylmorpholine N-oxide monohydrate, OsO₄; 2.) NaHSO₃ / 1.) acetone, H₂O, t-BuOH, r.t., 2 d; 2.) H₂O, r.t., 2 h

2: 94 percent / p-TsOH monohydrate / CH₂Cl₂ / 48 h / Heating

3: 86 percent / 2.) 0.1 M KOH / 1.) EtOH, 50 deg C; 2.) EtOH, r.t., 40.5 h

4: 1.) Zn, glacial acetic acid; 2.) 2 M NaOH / 1.) Et₂O, allowed to warm to r.t. during 24 h; 2.) 45 min

5: 92 percent / Na₂CO₃ / toluene / 24 h / Ambient temperature

With potassium hydroxide; sodium hydroxide; osmium(VIII) oxide; sodium carbonate; toluene-4-sulfonic acid; sodium hydrogensulfite; acetic acid; 4-methylmorpholine N-oxide; zinc; In dichloromethane; toluene;
DOI:10.1002/hlca.19830660702