Benzoic acid, nickel(2+) salt, trihydrate

Base Information

• Chemical Name: Benzoic acid, nickel(2+) salt, trihydrate
• CAS No.: 6018-91-3
• Molecular Formula: 2C₇H₅O₂*3H₂O*Ni
• Molecular Weight: 354.967
• Mol file: 6018-91-3.mol

Synonyms:

Chemical Property of Benzoic acid, nickel(2+) salt, trihydrate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzoic acid, nickel(2+) salt, trihydrate

There total 2 articles about Benzoic acid, nickel(2+) salt, trihydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

nickel(II) nitrate hexahydrate + benzoic acid (65-85-0,8013-63-6) → nickel benzoate trihydrate (6018-91-3,99909-93-0)

Guidance literature:

With NaOH; In water; benzoic acid and NaOH dissolved in H2O; filtered; filtrate mixed with Nisalt in H2O;

DOI:10.1021/ic9020965

Reference yield: 72.0%

nickel(II) carbonate (719261-06-0) + water (7732-18-5) + benzoic acid (65-85-0,8013-63-6) → nickel benzoate trihydrate (6018-91-3,99909-93-0)

Guidance literature:

Heating;

DOI:10.1002/ejic.201501255

Reference yield:

2,6-diacetylpyridine dioxime + water (7732-18-5) + nickel benzoate trihydrate (6018-91-3,99909-93-0) → [Ni3(OH)(O2CC6H5)3(2,6-diacetylpyridine dioximato(2-))(2,6-diacetylpyridine dioxime)(H2O)]*1.25H2O

Guidance literature:

With Et₃N; In methanol; ligand and Ni compd. dissolved in distd. MeOH contg. small amt. of H2O; Et3N added; stirred for 2 h; filtered; crystd. by layering the filtrate with Et2O; elem. anal.;

DOI:10.1021/ic9020965

upstream raw materials:

benzoic acid

nickel(II) carbonate

water

Downstream raw materials:

Ni₅(benzoate)2(2,6-diacetylpyridinedioxime^(2-))2(2,6-diacetylpyridinedioxime^(1-))2(dicyanamide)2(methanol)2

Refernces

• 1、 Escuer, Albert,Esteban, Jordi,Aliaga-Alcalde, Nuria,Font-Bardia, Merce,Calvet, Teresa,Roubeau, Olivier,Teat, Simon J.. "First structural and magnetic studies of Ni clusters containing 2,6-diacetylpyridine-dioxime as a ligand". . p. 2259 - 2266. Retrieved 2010.