(S)-2-[(Diphenylphosphino)methyl]pyrrolidine

Base Information

Chemical Name:(S)-2-[(Diphenylphosphino)methyl]pyrrolidine
CAS No.:60261-46-3
Molecular Formula:C17H20NP
Molecular Weight:269.326
Hs Code.:2933990090
DSSTox Substance ID:DTXSID00460741
Nikkaji Number:J1.000.349K
Wikidata:Q82284888
Mol file:60261-46-3.mol

Synonyms:(S)-2-[(Diphenylphosphino)methyl]pyrrolidine;60261-46-3;Diphenyl-[[(2S)-pyrrolidin-2-yl]methyl]phosphane;(2S)-2-[(Diphenylphosphanyl)methyl]pyrrolidine;SCHEMBL667151;(S)-2-[(Diphenylphosphino)methyl]pyrrolidine, min. 97%;DTXSID00460741;MFCD16621443;CS-0086664;F82360

Suppliers and Price of (S)-2-[(Diphenylphosphino)methyl]pyrrolidine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
(S)-2-[(Diphenylphosphino)methyl]pyrrolidine, min. 97%
1g
$ 373.00

Strem Chemicals
(S)-2-[(Diphenylphosphino)methyl]pyrrolidine, min. 97%
250mg
$ 125.00

Sigma-Aldrich
(S)-2-[(Diphenylphosphino)methyl]pyrrolidine
250mg
$ 123.00

Arctom
(S)-2-[(Diphenylphosphino)methyl]pyrrolidine 98%
1g
$ 627.00

Arctom
(S)-2-[(Diphenylphosphino)methyl]pyrrolidine 98%
250mg
$ 204.00

American Custom Chemicals Corporation
(S)-2-[(DIPHENYLPHOSPHINO)METHYL]PYRROLIDINE 95.00%
1G
$ 898.04

American Custom Chemicals Corporation
(S)-2-[(DIPHENYLPHOSPHINO)METHYL]PYRROLIDINE 95.00%
250MG
$ 332.12

Total 10 raw suppliers

Chemical Property of (S)-2-[(Diphenylphosphino)methyl]pyrrolidine

Chemical Property:

Refractive Index:n20/D1.614
Boiling Point:387.1±15.0 °C(Predicted)
PKA:10.46±0.10(Predicted)
Flash Point:>110℃
PSA：25.62000
Density:1.043 g/mL at 25 °C
LogP:3.20010
Sensitive.:air sensitive
XLogP3:3.2
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:269.133336640
Heavy Atom Count:19
Complexity:238

Purity/Quality:

97% ^*data from raw suppliers

(S)-2-[(Diphenylphosphino)methyl]pyrrolidine, min. 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:C1CC(NC1)CP(C2=CC=CC=C2)C3=CC=CC=C3
Isomeric SMILES:C1C[C@H](NC1)CP(C2=CC=CC=C2)C3=CC=CC=C3
Uses Catalytic ligand in:Ru-catalyzed regioselective lactonization of unsymmetrical 1,4-diols to give lactone lignansPreparation of vinylindanecarboxaldehyde by asymmetric intramolecular allylation of propenylbenzenepropanal

Technology Process of (S)-2-[(Diphenylphosphino)methyl]pyrrolidine

There total 19 articles about (S)-2-[(Diphenylphosphino)methyl]pyrrolidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 135055-75-3
(S)-(-)-N-tert-butoxycarbonyl-2-<(diphenylphosphino)methyl>pyrrolidine

: 60261-46-3
(2S)-2-[(diphenylphosphino)methyl]pyrrolidine

Guidance literature:: With trifluoroacetic acid; at 0 ℃; for 2h;
DOI:10.1248/cpb.39.616

Reference yield: 65.0%

: 1438408-68-4
(S)-2-((diphenylphosphino)methyl)pyrrolidine-1-sulfonic acid

: 60261-46-3
(2S)-2-[(diphenylphosphino)methyl]pyrrolidine

Guidance literature:: With hydrogenchloride; at 85 ℃; for 16h; Inert atmosphere;
DOI:10.1039/c3ob27460h

Reference yield: 65.0%

: 132635-95-1
5-(S)-<3.3.0>-1-aza-2-thia-3-oxabicyclooctane-2,2-dioxide

: 603-35-0
triphenylphosphine

: 60261-46-3
(2S)-2-[(diphenylphosphino)methyl]pyrrolidine

Guidance literature:: 5-(S)-<3.3.0>-1-aza-2-thia-3-oxabicyclooctane-2,2-dioxide; triphenylphosphine; With lithium; In tetrahydrofuran;

With hydrogenchloride; at 100 ℃; for 17h;
DOI:10.1039/c3dt33039g