Silver, iodo(triphenylphosphine)-

Base Information

• Chemical Name: Silver, iodo(triphenylphosphine)-
• CAS No.: 61026-08-2
• Molecular Formula: C18H15AgIP
• Molecular Weight: 497.064
• Mol file: 61026-08-2.mol

Synonyms:

Chemical Property of Silver, iodo(triphenylphosphine)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silver, iodo(triphenylphosphine)-

There total 1 articles about Silver, iodo(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

((13)C-N-mesityl-N'-methylimidazolylidene)silver(I) iodide + triphenylphosphine (603-35-0) → iodotris(triphenylphosphine)silver(I) (17116-27-7) + (triphenylphosphine)silver iodide (61026-08-2) + bis(triphenylphosphine)silver iodide + bis((13)C-N-mesityl-N'-methylimidazolylidene)silver(I) iodide

Guidance literature:

In dichloromethane-d2; under inert atmosphere; PPh3 added to soln. of Ag complex in CD2Cl2; monitored by (13)C NMR spectra;

DOI:10.1021/om300340w

Reference yield: 88.0%

(triphenylphosphine)silver iodide (61026-08-2) + Pt(CH2(P(C6H5)2)2)2(CH3)2 (84663-33-2) → Pt(CH3)2((C6H5)2PCH2P(C6H5)2)2Ag(1+)*I(1-)=Pt(CH3)2((C6H5)2PCH2P(C6H5)2)2AgI

Guidance literature:

In not given; Ag deriv. adding to Pt complex at -30°C; identified by elem. anal. and NMR spectrum;

DOI:10.1039/c39820001313

Reference yield: 73.0%

2,2,2,3,3,3,4,4,4,5,5,5-dodecacarbonyl-1,2,3;1,2,4-di-μ3-hydrido-1-triphenylphosphine-1,3,4-μ3-(triphenylphosphinecuprio)-cyclo-coppertetraruthenium + (triphenylphosphine)silver iodide (61026-08-2) → 2,2,2,3,3,3,4,4,4,5,5,5-dodecacarbonyl-1,2,3;1,2,4-di-μ3-hydrido-1-triphenylphosphine-1,3,4-μ3-(triphenylphosphineargentio)-cyclo-silvertetraruthenium

Guidance literature:

With TlPF₆; In dichloromethane; 4 equiv of AgIPPh3, 6 equiv. of TlPF6, CH2Cl2, stirring for 2 h;; filtered, chromd. on alumina column at -20°C, eluent CH2Cl2-light petroleum; recrystd. from CH2Cl2-light petroleum;;

DOI:10.1039/DT9870001001

upstream raw materials:

triphenylphosphine