2(5H)-Furanone, 4-(4-methyl-3-pentenyl)-

Base Information

• Chemical Name: 2(5H)-Furanone, 4-(4-methyl-3-pentenyl)-
• CAS No.: 61315-75-1
• Molecular Formula: C₁₀H₁₄O₂
• Molecular Weight: 166.22
• UNII: 38KIU3DE78
• DSSTox Substance ID: DTXSID30452932
• Nikkaji Number: J1.653.138C
• Mol file: 61315-75-1.mol

Synonyms:4-(4-methyl-3-pentenyl)-2(5H)-furanone;alpha,beta-acariolide

Chemical Property of 2(5H)-Furanone, 4-(4-methyl-3-pentenyl)-

Chemical Property:

• Vapor Pressure: 0.002mmHg at 25°C
• XLogP3: 2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 166.099379685
• Heavy Atom Count: 12
• Complexity: 232

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=CCCC1=CC(=O)OC1)C

Technology Process of 2(5H)-Furanone, 4-(4-methyl-3-pentenyl)-

There total 28 articles about 2(5H)-Furanone, 4-(4-methyl-3-pentenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

4-Hydroxy-4-(4-methyl-pent-3-enyl)-dihydro-furan-2-one (92215-07-1) → 4-(4-methylpent-3-en-1-yl)-2(5H)-furanone (61315-75-1)

Guidance literature:

With methanesulfonyl chloride; triethylamine; In dichloromethane; at 0 ℃;

DOI:10.1246/cl.1984.1261

Reference yield: 90.0%

C16H28O4 → 4-(4-methylpent-3-en-1-yl)-2(5H)-furanone (61315-75-1)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; water;

DOI:10.1021/acs.jafc.9b03391

Reference yield: 70.0%

2-(methylthio)-4-(4-methyl-3-pentenyl)furan (84735-64-8) → 4-(4-methylpent-3-en-1-yl)-2(5H)-furanone (61315-75-1)

Guidance literature:

With sulfuric acid; In methanol; for 1h; Heating;

DOI:10.1021/jo00194a028

upstream raw materials:

5-Hydroxy-4-(4-methyl-pent-3-enyl)-5H-furan-2-one

2-(methylthio)-4-(4-methyl-3-pentenyl)furan

(E)-4,8-dimethyl-2-(trimethylsilyloxy)nona-3,7-dienenitrile

5-Methoxy-4-(4-methyl-pent-3-enyl)-5H-furan-2-one

Downstream raw materials:

2-[(2Z,6E)-9-Furan-3-yl-6-methyl-2-(4-methyl-pent-3-enyl)-4-(toluene-4-sulfonyl)-nona-2,6-dienyloxy]-tetrahydro-pyran

(2Z,6E)-9-(3-Furyl)-6-methyl-2-(4-methyl-3-pentenyl)-4-(4-methylphenylsulfonyl)-2,6-nonadien-1-ol

3-(4-Methyl-3-phenylsulfanyl-pent-4-enyl)-furan