(1S)-2',3',8',8'aβ-Tetrahydro-5'-hydroxy-6'-methoxy-1'-methylspiro[2-cyclohexene-1,7'(1'H)-cyclopent[ij]isoquinolin]-4-one

Base Information

• Chemical Name: (1S)-2',3',8',8'aβ-Tetrahydro-5'-hydroxy-6'-methoxy-1'-methylspiro[2-cyclohexene-1,7'(1'H)-cyclopent[ij]isoquinolin]-4-one
• CAS No.: 10214-55-8
• Molecular Formula: C18H21 N O3
• Molecular Weight: 299.36424
• Mol file: 10214-55-8.mol

Synonyms:Linearisine(7CI,8CI); Spiro[2-cyclohexene-1,7'(1'H)-cyclopent[ij]isoquinolin]-4-one,2',3',8',8'a-tetrahydro-5'-hydroxy-6'-methoxy-1'-methyl-, (1S-trans)-;L-(+)-Linearisine

Chemical Property of (1S)-2',3',8',8'aβ-Tetrahydro-5'-hydroxy-6'-methoxy-1'-methylspiro[2-cyclohexene-1,7'(1'H)-cyclopent[ij]isoquinolin]-4-one

Chemical Property:

• Melting Point: 219-222°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

• Description: The empirical formula for this alkaloid from Croton linearis Jacq. was originally given as C 1 7H 1903N, representing it as a dihydrocrotonosine. This was later altered to that given above when it was shown that a methylimino group is present. The structure has now been confirmed as dihydro-N-methylcrotonosine. When crystallized from EtOH it forms anisotropic columns. The ultraviolet spectrum shows three absorption maxima at 228, 282 and 288 ffi/J. and the specific rotation in [o:Jf>8 + 116° (c 0.83, MeOH). The hydrochloride also forms colourless columnar crystals which decompose, without melting, above 300°C. One phenolic hydroxyl group is present and on methylation, the alkaloid yields Amuronine (q.v.).

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