Methyl 5-(trimethylsilyl)cyclohex-3-ene-1-carboxylate

Base Information

Chemical Name:Methyl 5-(trimethylsilyl)cyclohex-3-ene-1-carboxylate
CAS No.:61518-41-0
Molecular Formula:C₁₁H₂₀O₂Si
Molecular Weight:212.364
Hs Code.:
DSSTox Substance ID:DTXSID80508195

Synonyms:61518-41-0;Methyl 5-(trimethylsilyl)cyclohex-3-ene-1-carboxylate;DTXSID80508195

Suppliers and Price of Methyl 5-(trimethylsilyl)cyclohex-3-ene-1-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methyl 5-(trimethylsilyl)cyclohex-3-ene-1-carboxylate

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:212.123256411
Heavy Atom Count:14
Complexity:240

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1CC=CC(C1)[Si](C)(C)C

Technology Process of Methyl 5-(trimethylsilyl)cyclohex-3-ene-1-carboxylate

There total 4 articles about Methyl 5-(trimethylsilyl)cyclohex-3-ene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 59376-64-6
(2E)-3-(trimethylsilyl)prop-2-en-1-ol

: 61518-41-0
5-Trimethylsilanyl-cyclohex-3-enecarboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 78 percent / manganese dioxide / light petroleum / 12 h / Ambient temperature

2: 1.) magnesium / 1.) ether, reflux, 1 h, 2.) reflux, 4 h

3: 1.) toluene-p-sulphonic acid, 2.) hydroquinone / 1.) ether, room temperature, 1 h, 2.) 150 deg C, 24 h

With manganese(IV) oxide; toluene-4-sulfonic acid; magnesium; hydroquinone; In Petroleum ether;
DOI:10.1039/P19810002415

Reference yield:

: 58107-34-9,64081-45-4,33755-86-1
(E)-3-trimethylsilyl-2-propenal

: 61518-41-0
5-Trimethylsilanyl-cyclohex-3-enecarboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) magnesium / 1.) ether, reflux, 1 h, 2.) reflux, 4 h

2: 1.) toluene-p-sulphonic acid, 2.) hydroquinone / 1.) ether, room temperature, 1 h, 2.) 150 deg C, 24 h

With toluene-4-sulfonic acid; magnesium; hydroquinone;
DOI:10.1039/P19810002415

Reference yield:

: 71404-34-7
(E)-1,4-bis(trimethylsilyl)but-3-en-2-ol

: 292638-85-8,9003-21-8,96-33-3
acrylic acid methyl ester

: 61518-39-6
2-Trimethylsilanyl-cyclohex-3-enecarboxylic acid methyl ester

: 61518-41-0
5-Trimethylsilanyl-cyclohex-3-enecarboxylic acid methyl ester

Guidance literature:: With toluene-4-sulfonic acid; hydroquinone; Yield given. Multistep reaction; 1.) ether, room temperature, 1 h, 2.) 150 deg C, 24 h;
DOI:10.1039/P19810002415