Bromotris(2,4,6-trimethylphenyl)stannane

Base Information

Chemical Name:Bromotris(2,4,6-trimethylphenyl)stannane
CAS No.:6166-12-7
Molecular Formula:C27H33BrSn
Molecular Weight:556.173
Hs Code.:
DSSTox Substance ID:DTXSID40521401
Wikidata:Q82385839

Synonyms:Bromotris(2,4,6-trimethylphenyl)stannane;6166-12-7;DTXSID40521401

Suppliers and Price of Bromotris(2,4,6-trimethylphenyl)stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Bromotris(2,4,6-trimethylphenyl)stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:556.07877
Heavy Atom Count:29
Complexity:437

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=C(C(=C1)C)[Sn](C2=C(C=C(C=C2C)C)C)(C3=C(C=C(C=C3C)C)C)Br)C

Technology Process of Bromotris(2,4,6-trimethylphenyl)stannane

There total 3 articles about Bromotris(2,4,6-trimethylphenyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

: 7789-67-5
stannic bromide

: 2633-66-1
2-mesitylmagnesium bromide

: 6166-12-7
tris(2,4,6-trimethylphenyl)tin(IV) bromide

: 144650-37-3
(C₆H₂(CH₃)3)2SnBr₂

Guidance literature:: With water; hydrogen bromide; In diethyl ether; toluene; dropwise addn. of mesitylmagnesium bromide soln. (Et2O) to SnBr4 (toluene), refluxing (10 h), H2O and HBr (10 % aq.) addn., filtering; washing (H2O, NaHCO3 aq., H2O), drying (MgSO4), evapn., crystn. om MeOHaddn.;
DOI:10.1021/ja990389u

Reference yield: 30.6%

: 576-83-0
2,4,6-trimethylphenyl bromide

: 7789-67-5
stannic bromide

: 6166-12-7
tris(2,4,6-trimethylphenyl)tin(IV) bromide

Guidance literature:: With Mg; In tetrahydrofuran; toluene; addn. of SnBr4 in toluene to a Grignard-soln. of Mg and of mesityl bromide in THF, refluxing for 3 h, hydrolysis with aq. soln. of HBr; extn. of aq. phase with diethyl ether, concn., crystn. from acetone;
DOI:10.1016/0022-328X(89)85162-9

Reference yield:

: 56797-46-7
trimesityltin hydride

: 2695-47-8
6-Bromo-1-hexene

: 592-41-6,25067-06-5
1-hexene

: 6166-12-7
tris(2,4,6-trimethylphenyl)tin(IV) bromide

: 96-37-7
methyl-cyclopentane

Guidance literature:: With 1-iodoundecane; In dodecane; React. performed at 50°C in mixt. of dodecane and naphtalene under Ar.; Ratio of 1-hexene: methylcyclopentane >20:1; Kinetics;
DOI:10.1021/om00100a021