Diethyl (1R,2R)-4-oxocyclohexane-1,2-dicarboxylate

Base Information

Chemical Name:Diethyl (1R,2R)-4-oxocyclohexane-1,2-dicarboxylate
CAS No.:61692-24-8
Molecular Formula:C₁₂H₁₈O₅
Molecular Weight:242.272
Hs Code.:
DSSTox Substance ID:DTXSID10555233
Wikidata:Q82436528

Synonyms:Diethyl (1R,2R)-4-oxocyclohexane-1,2-dicarboxylate;61692-24-8;DTXSID10555233

Suppliers and Price of Diethyl (1R,2R)-4-oxocyclohexane-1,2-dicarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Diethyl (1R,2R)-4-oxocyclohexane-1,2-dicarboxylate

Chemical Property:

XLogP3:0.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:6
Exact Mass:242.11542367
Heavy Atom Count:17
Complexity:310

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1CCC(=O)CC1C(=O)OCC
Isomeric SMILES:CCOC(=O)[C@@H]1CCC(=O)C[C@H]1C(=O)OCC

Technology Process of Diethyl (1R,2R)-4-oxocyclohexane-1,2-dicarboxylate

There total 5 articles about Diethyl (1R,2R)-4-oxocyclohexane-1,2-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 141-05-9
Diethyl maleate

: 1726-61-0,61692-24-8,91766-14-2,113251-38-0
diethyl cis-1,2-cyclohexan-4-onedicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 39 percent / neat (no solvent) / 1.) 120 deg C, 48 h, 2.) 160 deg C, 24 h

In neat (no solvent);
DOI:10.1021/ja00412a024

Reference yield:

: 61692-31-7,61692-32-8
diethyl cis-4-trimethylsilyloxy-4-cyclohexene-1,2-dicarboxylate

: 1726-61-0,61692-24-8,91766-14-2,113251-38-0
diethyl cis-1,2-cyclohexan-4-onedicarboxylate

Guidance literature:: With methanol;
DOI:10.1016/S0040-4039(01)85493-9

Reference yield:

: 1726-39-2
4α,5α-Epoxy-cyclohexan-1β,2β-dicarbonsaeure-diethylester

: 1726-61-0,61692-24-8,91766-14-2,113251-38-0
diethyl cis-1,2-cyclohexan-4-onedicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: H₂, H₂SO₄ / PtO₂

2: CrO₃

With chromium(VI) oxide; sulfuric acid; hydrogen; platinum(IV) oxide;
DOI:10.1039/jr9640005526