4-Cyclohexyl-4-methoxy-1,1-dimethyl-1,4-dihydrosiline

Base Information

• Chemical Name: 4-Cyclohexyl-4-methoxy-1,1-dimethyl-1,4-dihydrosiline
• CAS No.: 61739-48-8
• Molecular Formula: C₁₄H₂₄OSi
• Molecular Weight: 236.429
• DSSTox Substance ID: DTXSID40500716

Synonyms:61739-48-8;4-Cyclohexyl-4-methoxy-1,1-dimethyl-1,4-dihydrosiline;DTXSID40500716

Chemical Property of 4-Cyclohexyl-4-methoxy-1,1-dimethyl-1,4-dihydrosiline

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 236.159641919
• Heavy Atom Count: 16
• Complexity: 282

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1(C=C[Si](C=C1)(C)C)C2CCCCC2

Technology Process of 4-Cyclohexyl-4-methoxy-1,1-dimethyl-1,4-dihydrosiline

There total 2 articles about 4-Cyclohexyl-4-methoxy-1,1-dimethyl-1,4-dihydrosiline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1Z,4Z)-(3R)-3-Cyclohexyl-1,5-dilithio-3-methoxy-1,4-pentadien (347190-66-3) + dimethylsilicon dichloride (75-78-5,30107-43-8) → 4-cyclohexyl-4-methoxy-1,1-dimethyl-1,4-dihydro-siline (61739-48-8)

Guidance literature:

In diethyl ether;

Reference yield:

1,1-di-n-butyl-4-cyclohexyl-4-methoxy-1,4-dihydrostannane (51470-93-0) + dimethylsilicon dichloride (75-78-5,30107-43-8) → 4-cyclohexyl-4-methoxy-1,1-dimethyl-1,4-dihydro-siline (61739-48-8)

Guidance literature:

Multistep reaction; (i) nBuLi, pentane, (ii) /BRN= 605287/, Et₂O;

DOI:10.1016/S0022-328X(00)81285-1

Reference yield: 70.0%

4-cyclohexyl-4-methoxy-1,1-dimethyl-1,4-dihydro-siline (61739-48-8) → 1,1-dimethyl-1-silacyclohexa-2,5-dien-4-one (30518-19-5) + 4-Cyclohexyl-1,1-dimethyl-1-silacyclohexa-2,4-dien (71421-46-0)

Guidance literature:

at 600 ℃; under 14 - 16 Torr;

DOI:10.1016/S0022-328X(00)85615-6

upstream raw materials:

(1Z,4Z)-(3R)-3-Cyclohexyl-1,5-dilithio-3-methoxy-1,4-pentadien

dimethylsilicon dichloride

1,1-di-n-butyl-4-cyclohexyl-4-methoxy-1,4-dihydrostannane

Downstream raw materials:

4-Cyclohexyl-1,1-dimethyl-6-trimethylsilyl-1-silacyclohexa-2,4-dien

2-chloro-4-cyclohexyl-1,1-dimethyl-1,2-dihydro-siline

4-Cyclohexyl-1,1-dimethyl-1-silacyclohexa-2,4-dien

1,1-dimethyl-1-silacyclohexa-2,5-dien-4-one

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