diethyl (E)-2-triethylstannylbut-2-enedioate

Base Information

• Chemical Name: diethyl (E)-2-triethylstannylbut-2-enedioate
• CAS No.: 3422-67-1
• Molecular Formula: C14H26O4Sn
• Molecular Weight: 377.0638
• NSC Number: 227349
• DSSTox Substance ID: DTXSID70421642
• Mol file: 3422-67-1.mol

Synonyms:NSC227349;3422-67-1;DTXSID70421642;NSC-227349

Chemical Property of diethyl (E)-2-triethylstannylbut-2-enedioate

Chemical Property:

• Vapor Pressure: 1.84E-05mmHg at 25°C
• Boiling Point: 363.2°Cat760mmHg
• Flash Point: 173.4°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 10
• Exact Mass: 378.085312
• Heavy Atom Count: 19
• Complexity: 324

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC(=O)C=C(C(=O)OCC)[Sn](CC)(CC)CC
• Isomeric SMILES: CCOC(=O)/C=C(\C(=O)OCC)/[Sn](CC)(CC)CC

Technology Process of diethyl (E)-2-triethylstannylbut-2-enedioate

There total 5 articles about diethyl (E)-2-triethylstannylbut-2-enedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

triethylstannane (997-50-2) + acetylenedicarboxylic acid diethyl ester (762-21-0) → Triethyl-<1.2-bis-ethoxycarbonyl-vinyl>-zinn (3422-67-1,4276-30-6,6150-37-4)

Guidance literature:

0°C, molar ratio = 1:2;; trans:cis=9:1;;

DOI:10.1016/S0022-328X(00)83731-6 DOI:10.1016/S0022-328X(00)83730-4

Reference yield:

triethylstannane (997-50-2) + acetylenedicarboxylic acid diethyl ester (762-21-0) → trans-Diethyl-(triethylstannyl-ethylen)-dicarboxylat (3422-67-1,4276-30-6,6150-37-4)

Guidance literature:

In not given;

Reference yield:

→ trans-Diethyl-(triethylstannyl-ethylen)-dicarboxylat (3422-67-1,4276-30-6,6150-37-4)

Guidance literature:

Acetylen-dicarbonsaeure-diethylester, Triethyl-stannan, N2 ( neben geringen Mengen Triethylstannyl-maleinsaeure-diethylester);

DOI:10.1016/S0022-328X(00)83730-4

upstream raw materials:

triethylstannane

acetylenedicarboxylic acid diethyl ester