1H-Pyrrole, 2-(diphenylphosphino)-

Base Information

Chemical Name:1H-Pyrrole, 2-(diphenylphosphino)-
CAS No.:61958-35-8
Molecular Formula:C16H14NP
Molecular Weight:251.268
Hs Code.:
DSSTox Substance ID:DTXSID20477098
Nikkaji Number:J1.228.721F
Wikidata:Q82309263

Synonyms:1H-Pyrrole, 2-(diphenylphosphino)-;61958-35-8;SCHEMBL1557675;DTXSID20477098

Suppliers and Price of 1H-Pyrrole, 2-(diphenylphosphino)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 1H-Pyrrole, 2-(diphenylphosphino)-

Chemical Property:

XLogP3:3.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:251.086386449
Heavy Atom Count:18
Complexity:226

Purity/Quality:: 98%,99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CN3

Technology Process of 1H-Pyrrole, 2-(diphenylphosphino)-

There total 4 articles about 1H-Pyrrole, 2-(diphenylphosphino)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 856702-63-1
N-(tert-butoxycarbonyl)-2-(diphenylphosphino)pyrrole

: 61958-35-8
diphenyl(2-pyrrolyl)phosphine

Guidance literature:: With sodium methylate; In tetrahydrofuran; methanol; at 0 - 23 ℃; for 0.666667h;
DOI:10.1021/ja042705x

Reference yield: 33.0%

: 109-97-7,30604-81-0
pyrrole

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 61958-35-8
diphenyl(2-pyrrolyl)phosphine

Guidance literature:: pyrrole; With ethylmagnesium bromide; In diethyl ether; at 20 ℃; for 1.5h; Cooling; Glovebox;

chloro-diphenylphosphine; In diethyl ether; at 20 ℃; Glovebox;
DOI:10.1016/j.poly.2014.06.047

Reference yield:

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 61958-35-8
diphenyl(2-pyrrolyl)phosphine

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi; TMP / tetrahydrofuran; hexane / 0.33 h / -78 °C

1.2: 52 percent / tetrahydrofuran; hexane / 21 h / -30 - 23 °C

2.1: 100 percent / NaOMe / tetrahydrofuran; methanol / 0.67 h / 0 - 23 °C

With n-butyllithium; sodium methylate; thymidine 5'-phosphate; In tetrahydrofuran; methanol; hexane;
DOI:10.1021/ja042705x