Borin, 1,4-dihydro-4,4-dimethyl-1-phenyl-

Base Information

Chemical Name:Borin, 1,4-dihydro-4,4-dimethyl-1-phenyl-
CAS No.:62496-51-9
Molecular Formula:C13H15B
Molecular Weight:182.073
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Borin, 1,4-dihydro-4,4-dimethyl-1-phenyl-

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of Borin, 1,4-dihydro-4,4-dimethyl-1-phenyl-

There total 1 articles about Borin, 1,4-dihydro-4,4-dimethyl-1-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 62496-43-9
3,3-Dimethyl-1,4-pentadiin

: 873-51-8
phenylborondichloride

: 62496-51-9
4,4-dimethyl-1-phenyl-1,4-dihydro-borinine

Guidance literature:: Multistep reaction; (i) Me₂SnH₂, hexane, (ii) /BRN= 2243576/;

Reference yield: 90.0%

: 12107-56-1
dichloro(cycloocta-1,5-diene)palladium (II)

: 1277-43-6,78206-33-4
cobaltocene

: 62496-51-9
4,4-dimethyl-1-phenyl-1,4-dihydro-borinine

: 74989-66-5
Pd(C₅H₄(CH₃)2BC₆H₅)2

Guidance literature:: With C₈H₁₂; In dichloromethane; (N2); to suspn. of Pd complex in COD was added boranederiv., then dropwise soln. of Co complex at -50°C within 1 h, mixt. was warmed up to room temp. within 2 h, CH2Cl2 was removed in vac., toluene added and soln. heated at 50°C for 4 h; soln. was filtered through Al2O3 at -78°C, solvent was removed and residue recrystd. from pentane; elem. anal.;
DOI:10.1016/S0022-328X(00)88552-6

Reference yield: 78.0%

: 13463-39-3,71564-36-8
tetracarbonyl nickel

: 62496-51-9
4,4-dimethyl-1-phenyl-1,4-dihydro-borinine

: 74982-02-8
Ni(C₅H₄(CH₃)2BC₆H₅)2

Guidance literature:: In toluene; (N2); soln. of Ni(CO)4 and ligand was slowly warmed up to 90°C bath temp. with stirring, mixt. was kept for 3 h at this temp.; volatiles were removed in vac. and residue chromd. (Al2O3, pentane); eluate was concd. and cooled to -78°C, yielding crystalline product; elem. anal.;
DOI:10.1016/S0022-328X(00)88552-6