(3S)-3-Formyl-2,3,4,7,8,8aβ-hexahydro-8β-(hydroxymethyl)-4β-[[(Z)-16-hydroxy-1-oxo-9-hexadecenyl]oxy]-8α-methyl-1H-3aα,7α-methanoazulene-6-carboxylic acid

Base Information

Chemical Name:(3S)-3-Formyl-2,3,4,7,8,8aβ-hexahydro-8β-(hydroxymethyl)-4β-[[(Z)-16-hydroxy-1-oxo-9-hexadecenyl]oxy]-8α-methyl-1H-3aα,7α-methanoazulene-6-carboxylic acid
CAS No.:54045-02-2
Molecular Formula:C31H48O7
Molecular Weight:532.70862
Hs Code.:
Mol file:54045-02-2.mol

(3S)-3-Formyl-2,3,4,7,8,8aβ-hexahydro-8β-(hydroxymethyl)-4β-[[(Z)-16-hydroxy-1-oxo-9-hexadecenyl]oxy]-8α-methyl-1H-3aα,7α-methanoazulene-6-carboxylic acid

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3S)-3-Formyl-2,3,4,7,8,8aβ-hexahydro-8β-(hydroxymethyl)-4β-[[(Z)-16-hydroxy-1-oxo-9-hexadecenyl]oxy]-8α-methyl-1H-3aα,7α-methanoazulene-6-carboxylic acid

Chemical Property:

PSA：121.13000
LogP:5.38250

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (3S)-3-Formyl-2,3,4,7,8,8aβ-hexahydro-8β-(hydroxymethyl)-4β-[[(Z)-16-hydroxy-1-oxo-9-hexadecenyl]oxy]-8α-methyl-1H-3aα,7α-methanoazulene-6-carboxylic acid

There total 5 articles about (3S)-3-Formyl-2,3,4,7,8,8aβ-hexahydro-8β-(hydroxymethyl)-4β-[[(Z)-16-hydroxy-1-oxo-9-hexadecenyl]oxy]-8α-methyl-1H-3aα,7α-methanoazulene-6-carboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1619-68-7,17278-80-7,18951-79-6
16-hydroxy-9-hexadecenoic acid

: 54045-02-2
(3S,3aS,4S,7R,8S,8aS)-3-Formyl-4-((Z)-16-hydroxy-hexadec-9-enoyloxy)-8-hydroxymethyl-8-methyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methano-azulene-6-carboxylic acid

Guidance literature:: Multi-step reaction with 4 steps

1: aq. H₂O₂, HCO₂H

2: PhCO₂H, HC(OEt)3 / (heating)

3: Ambient temperature

4: (i) (COCl)2, Py, benzene, (ii) /BRN= 6125709/, Py

With formic acid; dihydrogen peroxide; orthoformic acid triethyl ester; benzoic acid;
DOI:10.1016/0040-4020(78)80058-1

Reference yield:

: 533-87-9,6949-98-0,17941-34-3,18299-27-9,18951-77-4,33098-98-5,33098-99-6,37179-76-3,37179-77-4
threo-9,10,16-trihydroxyhexadecanoic acid

: 54045-02-2
(3S,3aS,4S,7R,8S,8aS)-3-Formyl-4-((Z)-16-hydroxy-hexadec-9-enoyloxy)-8-hydroxymethyl-8-methyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methano-azulene-6-carboxylic acid

Guidance literature:: Multi-step reaction with 5 steps

1: PhCO₂H, HC(OEt)3 / (heating)

2: aq. H₂O₂, HCO₂H

3: PhCO₂H, HC(OEt)3 / (heating)

4: Ambient temperature

5: (i) (COCl)2, Py, benzene, (ii) /BRN= 6125709/, Py

With formic acid; dihydrogen peroxide; orthoformic acid triethyl ester; benzoic acid;
DOI:10.1016/0040-4020(78)80058-1

Reference yield:

: 533-87-9
erythro-9,10,16-trihydroxyhexadecanoic acid

: 54045-02-2
(3S,3aS,4S,7R,8S,8aS)-3-Formyl-4-((Z)-16-hydroxy-hexadec-9-enoyloxy)-8-hydroxymethyl-8-methyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methano-azulene-6-carboxylic acid

Guidance literature:: Multi-step reaction with 3 steps

1: PhCO₂H, HC(OEt)3 / (heating)

2: Ambient temperature

3: (i) (COCl)2, Py, benzene, (ii) /BRN= 6125709/, Py

With orthoformic acid triethyl ester; benzoic acid;
DOI:10.1016/0040-4020(78)80058-1