2-(2-Methyl-2-propenyl)cyclododecan-1-one

Base Information

Chemical Name:2-(2-Methyl-2-propenyl)cyclododecan-1-one
CAS No.:62599-49-9
Molecular Formula:C16H28O
Molecular Weight:236.398
Hs Code.:
European Community (EC) Number:691-657-8
DSSTox Substance ID:DTXSID00562138
Nikkaji Number:J3.642.849J

Synonyms:62599-49-9;2-(2-Methyl-2-propenyl)cyclododecan-1-one;EC 691-657-8;2-methallyl-cyclododecanone;SCHEMBL1278415;DTXSID00562138;RSOBFXURUKCIKG-UHFFFAOYSA-N;2-(2-methylprop-2-enyl)cyclododecanone;NS00003573;2-(2-Methylprop-2-en-1-yl)cyclododecan-1-one

Suppliers and Price of 2-(2-Methyl-2-propenyl)cyclododecan-1-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 2-(2-Methyl-2-propenyl)cyclododecan-1-one

Chemical Property:

XLogP3:5.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:236.214015512
Heavy Atom Count:17
Complexity:242

Purity/Quality:: 99.9% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=C)CC1CCCCCCCCCCC1=O

Technology Process of 2-(2-Methyl-2-propenyl)cyclododecan-1-one

There total 1 articles about 2-(2-Methyl-2-propenyl)cyclododecan-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 130624-34-9,134454-41-4,134454-42-5
(3aRS,13aSR)-3a,4,5,6,7,8,9,10,11,12,13,13a-dodecahydro-2-methyl-1H-cyclopentacyclododecen-13a-ol

: 22442-02-0,58643-72-4,58643-73-5
(Z)-3-methylcyclopentadec-3-en-1-one

: 58643-72-4
(E)-3-methylcyclopentadec-3-en-1-one

: 62599-49-9
2-(2'-methylprop-2'-enyl)cyclododecan-1-one

: 134381-40-1
2-(2'-methylprop-1'-enyl)cyclododecan-1-one

Guidance literature:: With potassium hydride; ammonium chloride; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given; 1a) HMPA, 4h, room temp., 1b) 120 deg C, 2h;
DOI:10.1002/hlca.19900730416

Reference yield:

: 62599-49-9
2-(2'-methylprop-2'-enyl)cyclododecan-1-one

: 36399-15-2
3-methyl-4⁽⁵⁾-cyclopentadecen-1-one

: 63314-79-4
3-methyl-5-cyclopentadecen-1-one

Guidance literature:: Multi-step reaction with 3 steps

1: aluminum oxide / 190 h / 280 - 330 °C / Inert atmosphere; Industry scale

2: hydrogen / 5% Pd/C / water / 8 h / 100 °C / 3750.38 Torr / Autoclave

3: dinitrogen monoxide / 4 h / 280 °C / 202520 Torr

With hydrogen; dinitrogen monoxide; aluminum oxide; 5% Pd/C; In water;

Reference yield:

: 62599-49-9
2-(2'-methylprop-2'-enyl)cyclododecan-1-one

: 80468-65-1
2-<2-methyl-3-(phenylsulfonyl)propyl>cyclododecanone

Guidance literature:: Multi-step reaction with 2 steps

1: AIBN / 10 h / 80 °C

2: 40percent CH₃CO₃H / 1,1,1-trichloro-ethane / 30 °C

With peracetic acid; 2,2'-azobis(isobutyronitrile); In 1,1,1-trichloroethane;
DOI:10.1002/hlca.19830660816