2-Propenal, 3-chloro-2-methyl-

Base Information

• Chemical Name: 2-Propenal, 3-chloro-2-methyl-
• CAS No.: 24443-11-6
• Molecular Formula: C4H5 Cl O
• Molecular Weight: 104.5349
• Nikkaji Number: J2.537.294H
• Mol file: 24443-11-6.mol

Synonyms:2-Propenal, 3-chloro-2-methyl-;24443-11-6;SCHEMBL9530721;(E)-2-Methyl-3-chloropropenal

Chemical Property of 2-Propenal, 3-chloro-2-methyl-

Chemical Property:

• Vapor Pressure: 6.46mmHg at 25°C
• Boiling Point: 139.3°Cat760mmHg
• Flash Point: 39.7°C
• Density: 1.081g/cm³
• XLogP3: 1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 104.0028925
• Heavy Atom Count: 6
• Complexity: 75.6

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=CCl)C=O
• Isomeric SMILES: C/C(=C\Cl)/C=O

Technology Process of 2-Propenal, 3-chloro-2-methyl-

There total 6 articles about 2-Propenal, 3-chloro-2-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

→ 3-chloro-2-methyl-propenal (24443-11-6)

Guidance literature:

With N-Bromosuccinimide; In tetrachloromethane; for 2h; Heating;

DOI:10.1055/s-1981-29500

Reference yield: 68.0%

3-chloro-2-methylpropenol (76539-14-5) → 3-chloro-2-methyl-propenal (24443-11-6)

Guidance literature:

With manganese(IV) oxide; In dichloromethane; for 6h;

DOI:10.1021/jo00220a013

Reference yield:

3-dimethylamino-2-methyl-acrylaldehyde (19125-76-9) → 3-chloro-2-methyl-propenal (24443-11-6)

Guidance literature:

With COCl₂; In chloroform;

upstream raw materials:

phosgene

3-dimethylamino-2-methyl-acrylaldehyde

3-methoxy-2-methyl-propenal

3-chloro-2-methylpropenol

Downstream raw materials:

((1S,6S)-6-Chloro-1,3-dimethyl-cyclohex-3-enyl)-methanol

((1S,6S)-6-Chloro-1,4-dimethyl-cyclohex-3-enyl)-methanol

((1S,6R)-6-Chloro-1,3-dimethyl-cyclohex-3-enyl)-methanol

((1S,6R)-6-Chloro-1,4-dimethyl-cyclohex-3-enyl)-methanol

Refernces

• 1、 Schulze, Klaus,Rentsch, Martina,Haufe, Guenter,Welsch, Thomas. "Zur Herstellung von β-Chlorovinylcarbonyl-Verbindungen aus γ-Chloroallyl-ethern". . p. 483 - 484. Retrieved 2007/10/02.